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鉴定一种新型反冲洗方法清洗超滤膜的性能和成本:低剂量次氯酸钠反冲洗。

Identification of performance and cost in a new backwash method to clean the UF membrane: backwashing with low dosage of NaClO.

机构信息

School of Water Resources and Hydropower Engineering, North China Electric Power University, Beijing, 102206, China.

Beijing Engineering Research Center for Wastewater Reuse, Beijing, 100124, China.

出版信息

Environ Sci Pollut Res Int. 2023 Dec;30(58):121983-121992. doi: 10.1007/s11356-023-31008-3. Epub 2023 Nov 14.

Abstract

Ultrafiltration (UF) is widely used in wastewater reclamation treatments. Conventional backwashing is usually performed at regular time intervals (10-120 min) with permeate and without the addition of chemicals. Chemical enhanced backwashing (CEB) is usually applied after 70-90 filtration cycles with added chemicals. These cleaning methods cause membrane fouling and require costly chemicals. Instead of conventional backwashing, we propose herein a new backwashing method involving backwashing the effluent with low doses of sodium hypochlorite (NaClO) named as BELN. The performance and cost of UF backwashing were investigated with Beijing wastewater reclamation treatment. The results showed that the transmembrane pressure (TMP) increased from 33.2 to 48.2 kPa during hydraulic backwashing after 80 filtration cycles but increased from 33.3 to 39.3 kPa during backwashing with a low NaClO content of 20 mg/L. It was also noticed that the hydraulic-irreversible fouling index decreased from 5.58 × 10 m/L to 3.58 × 10 m/L with the new method. According to the three-dimensional fluorescence excitation-emission (3D-EEM), the response increased from 11.9 to 15.2% with BELN. Protein-like material was identified as the main component causing membrane fouling by blocking the membrane pores. The results indicated that the low dosage of NaClO effectively stripped the fouling layer. Finally, based on an economic evaluation, the capacity of the UF process was increased from 76,959 to 109,133 m/d with the new method. The amount of NaClO consumed for Beijing wastewater reclamation treatment was similarly compared with the conventional backwashing in per year under BELN. The new method has good potential for application.

摘要

超滤(UF)广泛应用于废水回收处理。传统的反冲洗通常在定期时间间隔(10-120 分钟)进行,使用渗透物且不添加化学物质。化学增强反冲洗(CEB)通常在 70-90 个过滤循环后进行,并添加化学物质。这些清洁方法会导致膜污染,并需要昂贵的化学物质。我们在此提出了一种新的反冲洗方法,即用低剂量次氯酸钠(NaClO)反冲洗废水,称为 BELN,而不是传统的反冲洗。使用北京废水回收处理研究了 UF 反冲洗的性能和成本。结果表明,在 80 个过滤循环后的水力反冲洗过程中,跨膜压力(TMP)从 33.2 kPa 增加到 48.2 kPa,但在反冲洗过程中,当 NaClO 含量低至 20 mg/L 时,TMP 从 33.3 kPa 增加到 39.3 kPa。还注意到,新方法的水力不可逆污染指数从 5.58×10 m/L 降低到 3.58×10 m/L。根据三维荧光激发-发射(3D-EEM),BELN 的响应从 11.9%增加到 15.2%。蛋白质样物质被确定为主要的膜污染成分,通过堵塞膜孔导致膜污染。结果表明,低剂量的 NaClO 可有效去除污染层。最后,基于经济评估,新方法使 UF 工艺的处理能力从 76959 立方米/天增加到 109133 立方米/天。在 BELN 下,北京废水处理的 NaClO 消耗量与传统反冲洗相似。新方法具有良好的应用潜力。

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