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过滤模式和反冲洗水对超滤膜水力不可逆污染的影响。

Effect of filtration mode and backwash water on hydraulically irreversible fouling of ultrafiltration membrane.

作者信息

Chang Haiqing, Liu Baicang, Liang Heng, Yu Huarong, Shao Senlin, Li Guibai

机构信息

College of Architecture and Environment, Sichuan University, No. 2 Section 2 Chuanda Road, Chengdu 610207, PR China; Institute of New Energy and Low Carbon Technology, Sichuan University, No. 2 Section 2 Chuanda Road, Chengdu 610207, PR China.

State Key Laboratory of Urban Water Resource and Environment (SKLUWRE), Harbin Institute of Technology, No. 73 Huanghe Road, Nangang District, Harbin 150090, PR China.

出版信息

Chemosphere. 2017 Jul;179:254-264. doi: 10.1016/j.chemosphere.2017.03.122. Epub 2017 Mar 30.

Abstract

To investigate the effect of filtration mode and backwash water on ultrafiltration (UF) membrane performance, total fouling index (TFI) and hydraulic irreversible fouling index (HIFI) for constant pressure (CP) filtration and constant flux (CF) filtration were compared. Kaolin, humic acid (HA) and sodium alginate (SA) solutions were used as feed solutions, and then the fouled membranes were backwashed with UF permeate or ultrapure water. Results showed that when the kaolin solution was filtrated, the filtration mode had a limited effect on the membrane fouling, and low TFI and HIFI were observed. When HA and SA solutions were filtrated, the TFI of UF under CP mode was comparable to or slightly higher than that under CF mode. Higher TFI was observed at a hydrophobic membrane, a high filtration strength, a high feed concentration, a low pH, a high ionic strength, and a low Ca concentration. When the UF permeate was used as the backwash water, the HIFI for the UF operated under CF mode was significantly less than that under CP mode. Low irreversible fouling was obtained when the ultrapure water was used for backwashing, and the HIFI for the UF under different filtration modes was almost identical.

摘要

为研究过滤模式和反洗水对超滤(UF)膜性能的影响,比较了恒压(CP)过滤和恒通量(CF)过滤的总污染指数(TFI)和水力不可逆污染指数(HIFI)。使用高岭土、腐殖酸(HA)和海藻酸钠(SA)溶液作为进料溶液,然后用超滤透过液或超纯水对污染的膜进行反洗。结果表明,当过滤高岭土溶液时,过滤模式对膜污染的影响有限,且观察到较低的TFI和HIFI。当过滤HA和SA溶液时,CP模式下超滤的TFI与CF模式下相当或略高。在疏水膜、高过滤强度、高进料浓度、低pH值、高离子强度和低钙浓度下观察到较高的TFI。当使用超滤透过液作为反洗水时,CF模式下运行的超滤的HIFI明显小于CP模式下的。当使用超纯水进行反洗时,不可逆污染较低,不同过滤模式下超滤的HIFI几乎相同。

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