Martín-Hernández Edgar, Montero-Rueda Clara, Ruiz-Mercado Gerardo J, Vaneeckhaute Céline, Martín Mariano
Department of Chemical Engineering, University of Salamanca, Plza. Caídos 1-5, 37008 Salamanca, Spain.
BioEngine - Research Team on Green Process Engineering and Biorefineries, Chemical Engineering Department, Université Laval, 1065 Ave. de la Médecine, Québec, QC, G1V 0A6, Canada.
Sustain Prod Consum. 2023 Oct;41:49-63. doi: 10.1016/j.spc.2023.07.028.
Intensive livestock farming generates vast amounts of organic materials, which are an important source of nitrogen releases. These anthropogenic nitrogen releases contribute to multiple environmental problems, including eutrophication of water systems, contamination of drinking water sources, and greenhouse gas emissions. Nitrogen recovery and recycling are technically feasible, and there exists a number of processes for nitrogen recovery from livestock material in the form of different products. In this work, a multi-scale techno-economic assessment of techniques for nitrogen recovery and recycling is performed. The assessment includes a material flow analysis of each process, from material collection to final treatment, to determine nitrogen recovery efficiency, losses, and recovery cost, as well as an environmental cost-benefit analysis to compare the nitrogen recovery cost versus the economic losses derived from its uncontrolled release into the environment. The results show that transmembrane chemisorption process results in the lowest recovery cost, 3.4-10.4 USD per kilogram of nitrogen recovered in the range of studied processing scales. The recovery of nitrogen from livestock material through three technologies, i.e., transmembrane chemisorption, MAPHEX, and stripping in packed bed, reveales to be cost-effective. Since the economic losses due to the harmful effects of nitrogen into the environment are estimated at 32-35 USD per kilogram of nitrogen released, nitrogen recycling is an environmentally and economically beneficial approach to reduce nutrient pollution caused by livestock operations.
集约化畜牧业产生大量有机物质,这些物质是氮释放的重要来源。这些人为的氮释放导致了多种环境问题,包括水体富营养化、饮用水源污染和温室气体排放。氮的回收和再循环在技术上是可行的,并且存在许多从牲畜粪便中以不同产品形式回收氮的工艺。在这项工作中,对氮回收和再循环技术进行了多尺度技术经济评估。评估包括对每个过程从物料收集到最终处理的物质流分析,以确定氮回收效率、损失和回收成本,以及环境成本效益分析,以比较氮回收成本与因氮无控制排放到环境中而产生的经济损失。结果表明,跨膜化学吸附过程的回收成本最低,在所研究的处理规模范围内,每回收一公斤氮的成本为3.4 - 10.4美元。通过跨膜化学吸附、MAPHEX和填充床汽提这三种技术从牲畜粪便中回收氮被证明具有成本效益。由于氮对环境有害影响造成的经济损失估计为每释放一公斤氮32 - 35美元,氮再循环是减少畜牧业运营造成的养分污染的一种环境和经济上有益的方法。