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Reduction-induced hapticity increase in a silacycle-bridged biaryl-based ligand coordinated to an iron center.

作者信息

Suga Yuto, Sunada Yusuke

机构信息

Department of Applied Chemistry, School of Engineering, The University of Tokyo, 4-6-1, Komaba, Meguro-ku, Tokyo 153-8505, Japan.

Institute of Industrial Science, The University of Tokyo, 4-6-1, Komaba, Meguro-ku, Tokyo 153-8505, Japan.

出版信息

Dalton Trans. 2024 Jan 16;53(3):862-865. doi: 10.1039/d3dt03788f.

DOI:10.1039/d3dt03788f
PMID:37987085
Abstract

An Fe(II) bromide complex supported by a bidentate phosphine ligand and an η(C)-coordinated six-membered silacycle-bridged biphenyl-based ligand is converted upon reduction into an Fe(I) complex in which the hapticity of the silacycle-based ligand increases from η to η.

摘要

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