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SiGe/Si多层结构的界面研究:不同外延工艺条件的影响

Interface Investigation on SiGe/Si Multilayer Structures: Influence of Different Epitaxial Process Conditions.

作者信息

Kong Zhenzhen, Song Yanpeng, Wang Hailing, Liu Xiaomeng, Wang Xiangsheng, Liu Jinbiao, Li Ben, Su Jiale, Tan Xinguang, Luan Qingjie, Lin Hongxiao, Ren Yuhui, Zhang Yiwen, Liu Jingxiong, Li Junfeng, Du Anyan, Radamson Henry H, Zhao Chao, Ye Tianchun, Wang Guilei

机构信息

Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, P. R. China.

Microelectronics Institute, University of Chinese Academy of Sciences, Beijing 100049, P. R. China.

出版信息

ACS Appl Mater Interfaces. 2023 Dec 6;15(48):56567-56574. doi: 10.1021/acsami.3c14168. Epub 2023 Nov 21.

Abstract

SiGe/Si multilayer is the core structure of the active area of gate-all-around field-effect transistors and semiconductor quantum computing devices. In this paper, high-quality SiGe/Si multilayers have been grown by a reduced-pressure chemical vapor deposition system. The effects of temperature, pressure, interface processing (dichlorosilane (SiHCl, DCS) and hydrogen chloride (HCl)) on improving the transition thickness of SiGe to Si interfaces were investigated. The interface quality was characterized by transmission electron microscopy/atomic force microscopy/high-resolution X-ray diffraction methods. It was observed that limiting the migration of Ge atoms in the interface was critical for optimizing a sharp interface, and the addition of DCS was found to decrease the interface transition thickness. The change of the interfacial transition layer is not significant in the short treatment time of HCl. When the processing time of HCl is increased, the internal interface is optimized to a certain extent but the corresponding film thickness is also reduced. This study provides technical support for the acquisition of an abrupt interface and will have a very favorable influence on the performance improvement of miniaturized devices in the future.

摘要

硅锗/硅多层结构是全栅场效应晶体管和半导体量子计算设备有源区的核心结构。本文利用减压化学气相沉积系统生长了高质量的硅锗/硅多层结构。研究了温度、压力、界面处理(二氯硅烷(SiHCl,DCS)和氯化氢(HCl))对改善硅锗与硅界面过渡厚度的影响。通过透射电子显微镜/原子力显微镜/高分辨率X射线衍射方法对界面质量进行了表征。研究发现,限制锗原子在界面处的迁移对于优化陡峭界面至关重要,并且发现添加DCS可减小界面过渡厚度。在HCl短处理时间内,界面过渡层的变化不显著。当HCl处理时间增加时,内部界面在一定程度上得到优化,但相应的膜厚也会减小。本研究为获得突变界面提供了技术支持,并将对未来小型化器件的性能提升产生非常有利的影响。

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