High-Pressure Synthesis of a High-Pressure Phase of MnN Having NiAs-Type Structure.

A novel high-pressure phase of manganese mononitride, NiAs-type MnN, was successfully synthesized through a pressure-induced phase transition from a tetragonal distorted NaCl-type MnN at pressures above approximately 55 GPa. High-pressure experiments, including starting material preparation, were conducted using a laser-heated diamond anvil cell. This result is the first example of a nitride with a structural phase transition from the distorted NaCl-type to the NiAs-type structure. Upon decompression after the phase transition to NiAs-type structure, the NiAs-type MnN underwent a structural change to the distorted NaCl-type phase, indicating the phase transition was reversible. NiAs-type MnN has a higher density and bulk modulus in comparison to the distorted NaCl-type one. The phase transition pressure of MnN is lower than that of oxides, such as FeO and MnO, which show a structural phase transition from a NaCl-type to a NiAs-type structure. It is suggested that this is due to the lattice distortion caused by antiferromagnetic ordering.