von Köller Heinrich F, Geffers Finn J, Kalvani Pedram, Foraita Adrian, Loß Patrick-Eric J, Butschke Burkhard, Jones Peter G, Werz Daniel B
Albert-Ludwigs-Universität Freiburg, Institute of Organic Chemistry, Albertstraße 21, 79104 Freiburg, Germany.
Technische Universität Braunschweig, Institute of Organic Chemistry, Hagenring 30, 38106 Braunschweig, Germany.
Chem Commun (Camb). 2023 Dec 12;59(99):14697-14700. doi: 10.1039/d3cc04913b.
Here, we present a new route to dyes of the BODIPY family. We first built up a -Boc-protected dipyrromethene scaffold an aminopalladation cascade. Subsequentially, the pyrrole moiety was deprotected and the BF unit inserted. Depending on the terminating reaction, BODIPYs with either aryl or alkynyl moieties were accessible.
在此，我们展示了一种合成BODIPY家族染料的新途径。我们首先通过氨基钯化级联反应构建了一个-Boc保护的二吡咯亚甲基支架。随后，吡咯部分被脱保护并插入BF单元。根据终止反应的不同，可以得到带有芳基或炔基部分的BODIPY染料。
