螺[吲哚啉]-甲烷富勒烯的合成 脱氧氟促进1,2-(3-吲哚基)-富勒醇的脱氧环丙烷化反应。
Synthesis of spiro[indolenine]-methanofullerenes Deoxofluor promoted deoxygenative cyclopropanation of 1,2-(3-indole)-fullerenols.
作者信息
Ma Wen-Bin, Wang Long-Ge, Chen Shou-Rui, Zhang Xiang, Xuan Jun, Li Fei
机构信息
Department of Chemistry, Anhui University; Key Laboratory of Structure and Functional Regulation of Hybrid Materials (Anhui University), Ministry of Education; Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials and Key Laboratory of Functional Inorganic Materials of Anhui Province, Hefei, Anhui 230601, China.
出版信息
Org Biomol Chem. 2023 Dec 6;21(47):9459-9462. doi: 10.1039/d3ob01697h.
Deoxofluor-promoted intramolecular cyclopropanation of 1,2-(3-indole)fullerenols has been developed as a straightforward and efficient protocol for the synthesis of various spiro[indolenine]-methanofullerenes. This approach exhibits low cost, operational simplicity, and convenient conditions, and thus has potential application value.
脱氧氟促进的1,2-(3-吲哚基)富勒醇分子内环丙烷化反应已被开发为一种直接且高效的合成各种螺[吲哚啉]-亚甲基富勒烯的方法。该方法具有成本低、操作简单和条件便利的特点，因此具有潜在的应用价值。
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