通过加成-消除机理实现的[60]富勒烯的亲核环丙烷化反应。
Nucleophilic cyclopropanation of [60]fullerene by the addition-elimination mechanism.
作者信息
Biglova Yulya N, Mustafin Akhat G
机构信息
Ufa Institute of Chemistry, Russian Academy of Sciences Ufa Russian Federation
Department of Chemistry, Bashkir State University Ufa Russian Federation.
出版信息
RSC Adv. 2019 Jul 19;9(39):22428-22498. doi: 10.1039/c9ra04036f. eCollection 2019 Jul 17.
Abstract
Information on the synthesis of monofunctionalized methanofullerenes C obtained by the addition-elimination mechanism is generalized. The main reagents for cyclopropanation, mechanisms and optimal conditions for the processes, and the prospects for practical application of the products are considered.
摘要
概括了通过加成-消除机理合成单官能化甲烷富勒烯C的相关信息。考虑了环丙烷化的主要试剂、反应过程的机理和最佳条件，以及产物的实际应用前景。
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