Nanthagopal Murugan, Mouraliraman Devanadane, Han Yu-Ri, Ho Chang Won, Obregon Josue, Jung Jae-Yoon, Lee Chang Woo
Department of Chemical Engineering (Integrated Engineering Program), College of Engineering, Kyung Hee University, 1732 Deogyeong-daero, Giheung, Yongin 17104, Republic of Korea.
Department of Industrial and Management Systems Engineering, Kyung Hee University, 1732 Deogyeong-daero, Giheung, Yongin 17104, Republic of Korea.
Nanomaterials (Basel). 2023 Nov 16;13(22):2963. doi: 10.3390/nano13222963.
To simultaneously reduce the cost of environmental treatment of discarded food waste and the cost of energy storage materials, research on biowaste conversion into energy materials is ongoing. This work employs a solid-state thermally assisted synthesis method, transforming natural eggshell membranes (NEM) into nitrogen-doped carbon. The resulting NEM-coated LFP (NEM@LFP) exhibits enhanced electrical and ionic conductivity that can promote the mobility of electrons and Li-ions on the surface of LFP. To identify the optimal synthesis temperature, the synthesis temperature is set to 600, 700, and 800 °C. The NEM@LFP synthesized at 700 °C (NEM 700@LFP) contains the most pyrrolic nitrogen and has the highest ionic and electrical conductivity. When compared to bare LFP, the specific discharge capacity of the material is increased by approximately 16.6% at a current rate of 0.1 C for 50 cycles. In addition, we introduce innovative data-driven experiments to observe trends and estimate the discharge capacity under various temperatures and cycles. These data-driven results corroborate and support our experimental analysis, highlighting the accuracy of our approach. Our work not only contributes to reducing environmental waste but also advances the development of efficient and eco-friendly energy storage materials.
为了同时降低废弃食物垃圾的环境处理成本和储能材料的成本,将生物废料转化为能源材料的研究正在进行中。这项工作采用固态热辅助合成方法,将天然蛋壳膜(NEM)转化为氮掺杂碳。所得的NEM包覆的磷酸铁锂(NEM@LFP)表现出增强的电导率和离子电导率,可促进电子和锂离子在LFP表面的迁移。为了确定最佳合成温度,将合成温度设定为600、700和800℃。在700℃合成的NEM@LFP(NEM 700@LFP)含有最多的吡咯氮,并且具有最高的离子电导率和电导率。与裸LFP相比,该材料在0.1 C的电流速率下进行50次循环时,比放电容量提高了约16.6%。此外,我们引入了创新的数据驱动实验,以观察趋势并估计不同温度和循环下的放电容量。这些数据驱动的结果证实并支持了我们的实验分析,突出了我们方法的准确性。我们的工作不仅有助于减少环境废物,还推动了高效和环保储能材料的发展。