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含植物源天然添加剂的环氧树脂基材料,用于铁路运输。

Epoxy Resin-Based Materials Containing Natural Additives of Plant Origin Dedicated to Rail Transport.

作者信息

Masek Anna, Olejnik Olga, Czechowski Leszek, Kaźmierczyk Filip, Miszczak Sebastian, Węgier Aleksandra, Krauze Sławomir

机构信息

Institute of Polymer and Dye Technology, Lodz University of Technology, Stefanowskiego Str. 16, 90-537 Lodz, Poland.

Department of Strength of Materials, Lodz University of Technology, Stefanowskiego Str. 1/15, 90-537 Lodz, Poland.

出版信息

Materials (Basel). 2023 Nov 8;16(22):7080. doi: 10.3390/ma16227080.

Abstract

The presented study is focused on the modification of commercially available epoxy resin with flame retardants by means of using natural substances, including quercetin hydrate and potato starch. The main aim was to obtain environmentally friendly material dedicated to rail transport that is resistant to the aging process during exploitation but also more prone to biodegradation in environmental conditions after usage. Starch is a natural biopolymer that can be applied as a pro-ecological filler, which may contribute to degradation in environmental conditions, while quercetin hydrate is able to prevent a composite from premature degradation during exploitation. To determine the aging resistance of the prepared materials, the measurements of hardness, color, mechanical properties and surface free energy were performed before and after solar aging. To assess the mechanical properties of the composite material, one-directional tensile tests were performed for three directions (0, 90, 45 degrees referred to the plate edges). Moreover, the FT-IR spectra of pristine and aged materials were obtained to observe the changes in chemical structure. Furthermore, thermogravimetric analysis was conducted to achieve information about the impact of natural substances on the thermal resistance of the achieved composites.

摘要

本研究聚焦于通过使用包括水合槲皮素和马铃薯淀粉在内的天然物质,对市售环氧树脂进行阻燃改性。主要目的是获得一种环保材料,用于铁路运输,在使用过程中耐老化,且在使用后更易于在环境条件下生物降解。淀粉是一种天然生物聚合物,可作为生态友好型填料,有助于在环境条件下降解,而水合槲皮素能够防止复合材料在使用过程中过早降解。为了确定所制备材料的耐老化性,在太阳老化前后对硬度、颜色、机械性能和表面自由能进行了测量。为了评估复合材料的机械性能,对三个方向(相对于板材边缘为0、90、45度)进行了单向拉伸试验。此外,还获得了原始材料和老化材料的傅里叶变换红外光谱(FT-IR),以观察化学结构的变化。此外,进行了热重分析,以获取有关天然物质对所制备复合材料热阻影响的信息。

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