Plota-Pietrzak Angelika, Czechowski Leszek, Miszczak Sebastian, Masek Anna
Institute of Polymer and Dye Technology, Faculty of Chemistry, Lodz University of Technology, 90-537 Lodz, Poland.
Department of Strength of Materials, Lodz University of Technology, 90-537 Lodz, Poland.
Materials (Basel). 2024 Apr 16;17(8):1829. doi: 10.3390/ma17081829.
The subject of this research is the development of epoxy composites with a defined service life for the purpose of seat elements in rail vehicles, which will be more environmentally friendly. The produced materials based on epoxy resin filled with PLA or PLA and quercetin were subjected to solar aging tests for 800 h to investigate the impact of the additives used on the aging behavior of the epoxy matrix. Firstly, the TGA analysis showed that the use of the proposed additives allowed for the maintenance of the thermal stability of the epoxy resin. Moreover, based on an optical microscopy test, it was noticed that the introduction of PLA and PLA with quercetin did not contribute to an increase in matrix defects. The one-directional tensile tests carried out before and after solar aging showed that the presence of polylactide in epoxy composites causes a slight growth of the stiffness and strength. Based on contact angle and color change measurements, it was found that quercetin was oxidized, thus ensuring protection for the epoxy matrix. This phenomenon was confirmed by FTIR study, where the carbonyl index (CI) value for the R-PLA-Q composite was lower than for the reference sample. The obtained composite structures may be a good alternative to traditionally used systems as seat elements in rail vehicles, which are not only characterized by high aging resistance but are also more eco-friendly.
本研究的主题是开发用于铁路车辆座椅部件、具有确定使用寿命且更环保的环氧复合材料。对基于填充聚乳酸(PLA)或聚乳酸与槲皮素的环氧树脂所制备的材料进行了800小时的太阳老化试验,以研究所用添加剂对环氧基体老化行为的影响。首先,热重分析(TGA)表明,使用所提出的添加剂能够维持环氧树脂的热稳定性。此外,基于光学显微镜测试,发现引入聚乳酸以及聚乳酸与槲皮素并未导致基体缺陷增加。在太阳老化前后进行的单向拉伸试验表明,环氧复合材料中聚乳酸的存在会使刚度和强度略有增加。基于接触角和颜色变化测量发现,槲皮素被氧化,从而为环氧基体提供了保护。傅里叶变换红外光谱(FTIR)研究证实了这一现象,其中R-PLA-Q复合材料的羰基指数(CI)值低于参考样品。所获得的复合结构可能是铁路车辆座椅部件传统使用系统的良好替代品,这些复合结构不仅具有高耐老化性,而且更环保。