Rüttger Franziska, Stalke Dietmar, John Michael
Institute of Inorganic Chemistry, Georg-August-University of Göttingen, Germany.
Chem Commun (Camb). 2023 Dec 12;59(99):14657-14660. doi: 10.1039/d3cc05054h.
A new NMR method for structural verification and B resonance assignment in (car)borane clusters is presented, based on the measurement of B residual quadrupolar couplings (RQCs) in a stretched polystyrene (PS) gel. The method was applied to -carborane (BCH), a derivative thereof with reduced symmetry, -carborane and decaborane (BH).
本文提出了一种新的核磁共振（NMR）方法，用于（碳）硼烷簇合物的结构验证和硼核的共振归属，该方法基于在拉伸聚苯乙烯（PS）凝胶中测量硼的剩余四极耦合（RQC）。该方法应用于对-碳硼烷（BCH）、一种对称性降低的衍生物、-碳硼烷和癸硼烷（BH）。
