Kromer Kathrin, Lyu Chunhai, Door Menno, Filianin Pavel, Harman Zoltán, Herkenhoff Jost, Indelicato Paul, Keitel Christoph H, Lange Daniel, Novikov Yuri N, Schweiger Christoph, Eliseev Sergey, Blaum Klaus
Max-Planck-Institut für Kernphysik, 69117 Heidelberg, Germany.
Laboratoire Kastler Brossel, Sorbonne Université, CNRS, ENS-PSL Research University, Collège de France, Paris, France.
Phys Rev Lett. 2023 Dec 1;131(22):223002. doi: 10.1103/PhysRevLett.131.223002.
Highly charged ions (HCIs) offer many opportunities for next-generation clock research due to the vast landscape of available electronic transitions in different charge states. The development of extreme ultraviolet frequency combs has enabled the search for clock transitions based on shorter wavelengths in HCIs. However, without initial knowledge of the energy of the clock states, these narrow transitions are difficult to be probed by lasers. In this Letter, we provide experimental observation and theoretical calculation of a long-lived electronic state in Nb-like Pb^{41+} that could be used as a clock state. With the mass spectrometer PENTATRAP, the excitation energy of this metastable state is directly determined as a mass difference at an energy of 31.2(8) eV, corresponding to one of the most precise relative mass determinations to date with a fractional uncertainty of 4×10^{-12}. This experimental result agrees within 1σ with two partially different ab initio multiconfiguration Dirac-Hartree-Fock calculations of 31.68(13) eV and 31.76(35) eV, respectively. With a calculated lifetime of 26.5(5.3) days, the transition from this metastable state to the ground state bears a quality factor of 1.1×10^{23} and allows for the construction of a HCI clock with a fractional frequency instability of <10^{-19}/sqrt[τ].
