Reduced electron/hole recombination in Z-scheme nanostructure of zeolitic imidazolate framework-11/graphitic carbon nitride as photocatalyst under visible light.

In this research, for the first time, the synthesis of nanostructure of zeolitic imidazolate framework-11/graphitic carbon nitride (ZIF-11/g-CN X) with different weight of g-CN (X: 0.01, 0.1, 0.3 g) is reported. Their performance was compared in photocatalytic degradation of MB under visible light. Synthetic samples were characterized by X-Ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), X-ray photoelectron spectrometer (XPS), diffused reflectance spectroscopy (DRS), Field emission scanning electron microscopy (FE-SEM), Transmission electron microscope (TEM), Brunauer-Emmett-Teller (BET), Electrochemical Impedance Spectroscopy (EIS) and Photoluminescence (PL) analysis. Based on the results, Z-scheme ZIF-11/g-CN 0.3 was selected as the best sample. FESEM and TEM images indicated that g-CN sheets were complicated on the surface of ZIF-11 with rhombic dodecahedron (RHO) morphology. The surface area and band gap of ZIF-11/g-CN 0.3 was determined as 174.5 m/g and 2.58 eV, respectively. The recombination of charge carriers in the ZIF-11/g-CN 0.3 nanostructure was reduced. Photocatalytic degradation efficiency of MB (5 ppm), pH = 7, visible irradiation (120 W-60 min) using 0.1 g of ZIF-11/g-CN 0.3 was achieved 72.7% with first-order kinetic model and acceptable stability in three consecutive cycles. Further, the total organic carbon (TOC) removal rate by ZIF-11/g-CN 0.3 after 5 h were 66.5%.