基于碘鎓的氢氟烯烃骨架的区域选择性双亲核烯烃官能化反应。
Iodonium based regioselective double nucleophilic alkene functionalization of a hydrofluoroolefin scaffold.
作者信息
Csenki János T, Novák Zoltán
机构信息
MTA-ELTE "Lendület" Catalysis and Organic Synthesis Research Group, Eötvös Loránd University, Institute of Chemistry, Pázmány Péter stny. 1/A, Budapest H-1117, Hungary.
出版信息
Chem Commun (Camb). 2024 Jan 16;60(6):726-729. doi: 10.1039/d3cc04985j.
PMID:38112008
Abstract
Herein, we report a modular regioselective alkene difunctionalization strategy based on the use of hydrofluoroolefin (HFO) gas as fluorous feedstock material. The transformation of the HFO gas to iodonium salt creates vicinal electrophilic sites readily available for a broad range of nucleophiles.
摘要
在此，我们报道了一种基于使用氢氟烯烃（HFO）气体作为氟代原料的模块化区域选择性烯烃双官能团化策略。HFO气体转化为碘鎓盐会产生易于被多种亲核试剂利用的邻位亲电位点。
Zotero 插件