相邻铜中心对Fe-Mabiq电催化和光催化CO还原的影响。
Influence of a neighbouring Cu centre on electro- and photocatalytic CO reduction by Fe-Mabiq.
作者信息
Rickmeyer Kerstin, Huber Matthias, Hess Corinna R
机构信息
Department of Chemistry and Catalysis Research Center (CRC), Technical University of Munich, Garching 85748, Germany.
Faculty of Chemistry and Pharmacy, University of Regensburg, Regensburg 93053, Germany.
出版信息
Chem Commun (Camb). 2024 Jan 18;60(7):819-822. doi: 10.1039/d3cc04777f.
PMID:38113085
Abstract
Electrocatalytic and photocatalytic CO reduction by a heterobimetallic Cu/Fe-Mabiq complex were examined and compared to the monometallic [Fe(Mabiq)]. The neighbouring Cu-Xantphos unit leads to marked changes in the electrocatalytic mechanism and enhanced photocatalytic performance.
摘要
研究了异双金属Cu/Fe-Mabiq配合物的电催化和光催化CO还原，并与单金属[Fe(Mabiq)]进行了比较。相邻的Cu-Xantphos单元导致电催化机制发生显著变化，并提高了光催化性能。
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