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水合硅钙石负载壳聚糖对重金属离子的吸附性能及其机制研究

Simultaneous removal of calcium, cadmium and tetracycline from reverse osmosis wastewater by sycamore deciduous biochar, shell powder and polyurethane sponge combined with biofilm reactor.

机构信息

School of Environmental and Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China; Shaanxi Key Laboratory of Environmental Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China.

School of Environmental and Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China; Shaanxi Key Laboratory of Environmental Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China.

出版信息

Bioresour Technol. 2024 Feb;394:130215. doi: 10.1016/j.biortech.2023.130215. Epub 2023 Dec 19.

DOI:10.1016/j.biortech.2023.130215
PMID:38122995
Abstract

The treatment of reverse osmosis concentrate generated from urban industrial sewage for resource recovery has been hot. In this research, a biofilm reactor was constructed by combining sycamore deciduous biochar, shell powder, and polyurethane sponge loaded with Zobellella denitrificans sp. LX16. For ammonia nitrogen (NH-N), calcium (Ca), chemical oxygen demand (COD), cadmium (Cd), and tetracycline (TC), the removal efficiencies were 98.69 %, 83.95 %, 97.26 %, 98.34 %, and 69.12 % at a hydraulic retention time (HRT) of 4 h, pH of 7.0, and influent salinity, Ca, and TC concentrations of 1.0, 180.0, and 3.0 mg/L, respectively. The biofilm reactor packing has a three-dimensional structure to ensure good loading of microorganisms while promoting electron transfer and metabolic activity of microorganisms and increasing the pollutant tolerance and removal efficiency. The reactor provides a practical reference for the sedimentation of reverse osmosis concentrate to remove Cd and TC by microbial induced calcium precipitation (MICP).

摘要

从城市工业污水中回收反渗透浓缩液的处理一直备受关注。在这项研究中,通过将枫杨落叶生物炭、贝壳粉和负载 Zobellella denitrificans sp. LX16 的聚氨酯海绵组合,构建了一个生物膜反应器。在水力停留时间为 4 小时、pH 值为 7.0 以及进水盐度、Ca 和 TC 浓度分别为 1.0、180.0 和 3.0 mg/L 的条件下,对氨氮(NH-N)、钙(Ca)、化学需氧量(COD)、镉(Cd)和四环素(TC)的去除效率分别达到 98.69%、83.95%、97.26%、98.34%和 69.12%。生物膜反应器的填充具有三维结构,可确保微生物的良好负载,同时促进微生物的电子转移和代谢活性,提高污染物的耐受性和去除效率。该反应器为反渗透浓缩液通过微生物诱导碳酸钙沉淀(MICP)去除 Cd 和 TC 提供了实用参考。

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