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集料粒径对碱硅酸反应诱导膨胀的影响。

Impact of Aggregate Grain Size on ASR-Induced Expansion.

作者信息

Zapała-Sławeta Justyna

机构信息

Faculty of Civil Engineering and Architecture, Kielce University of Technology, Al. Tysiąclecia Państwa Polskiego 7, 25-314 Kielce, Poland.

出版信息

Materials (Basel). 2023 Dec 5;16(24):7506. doi: 10.3390/ma16247506.

Abstract

Alkali-silica reaction (ASR) is a sequence of complex chemical processes, resulting in the formation of alkali silica gels with high swelling ability. ASR leads to the expansion of concrete and the degradation of its microstructure. The susceptibility of aggregates to alkali reaction depends, among other factors, on the type and origin of the aggregate, the presence of reactive forms of silica, the mineral composition, and the geometric properties of the aggregate, such as shape and grain size. This study aimed to investigate the impact of the grain size of polymineral post-glacial gravel aggregate, originating from the northern regions of Poland, on its susceptibility to ASR. The expansion of mortars made from polymineral aggregate and the cracking of grains and cement matrix due to the occurring reactions were analyzed. Based on the conducted research, it was observed that the expansion of mortars depends on the grain size of the aggregate. It was demonstrated that the fraction of reactive aggregate generating the most significant elongation of mortars is in the range of 1.0-2.0 mm. The reaction of silica with alkalis continued until the depletion of reactive components in the aggregate. The relationship between the progress of corrosive processes and the grain size of the aggregate was evident in the form of different linear elongation increments of mortars over time. The expansion of mortars was caused by the swelling ASR gel, inducing stress in the grain and the surrounding cementitious paste.

摘要

碱-硅酸反应(ASR)是一系列复杂的化学过程,会导致形成具有高膨胀能力的碱硅胶。ASR会导致混凝土膨胀并使其微观结构退化。集料对碱反应的敏感性除其他因素外,还取决于集料的类型和来源、活性二氧化硅形式的存在、矿物成分以及集料的几何特性,如形状和粒度。本研究旨在调查源自波兰北部地区的多矿物冰后期砾石集料的粒度对其ASR敏感性的影响。分析了由多矿物集料制成的砂浆的膨胀以及由于发生的反应导致的颗粒和水泥基体的开裂。基于所进行的研究,观察到砂浆的膨胀取决于集料的粒度。结果表明,产生砂浆最大伸长率的活性集料部分在1.0 - 2.0毫米范围内。二氧化硅与碱的反应持续到集料中活性成分耗尽。腐蚀过程的进展与集料粒度之间的关系以砂浆随时间不同的线性伸长增量的形式明显体现。砂浆的膨胀是由膨胀的ASR凝胶引起的,在颗粒和周围的水泥浆中产生应力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b8e/10744678/f0f36af9ba88/materials-16-07506-g001.jpg

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