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超疏水性的挑战:环境促进的卡西 - 文泽尔转变与结构设计

The Challenge of Superhydrophobicity: Environmentally Facilitated Cassie-Wenzel Transitions and Structural Design.

作者信息

Zhong Xin, Xie Shangzhen, Guo Zhiguang

机构信息

Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials, Hubei University, Wuhan, 430062, China.

State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, China.

出版信息

Adv Sci (Weinh). 2024 Mar;11(10):e2305961. doi: 10.1002/advs.202305961. Epub 2023 Dec 25.

Abstract

Superhydrophobic materials can be used in various fields to optimize production and life due to their unique surface wetting properties. However, under certain pressure and perturbation conditions, the droplets deposited on superhydrophobic materials are prone to change from Cassie state to Wenzel state, which limits the practical applications of the materials. In recent years, a large number of works have investigated the transition behavior, transition mechanism, and influencing factors of the wetting transition that occurs when a superhydrophobic surface is under a series of external environments. Based on these works, in this paper, the phenomenon and kinetic behavior of the destruction of the Cassie state and the mechanism of the wetting transition are systematically summarized under external conditions that promote the wetting transition on the material surface, including pressure, impact, evaporation, vibration, and electric wetting. In addition, superhydrophobic surface morphology has been shown to directly affect the duration of the Cassie state. Based on the published work the effects of specific morphology on the Cassie state, including structural size, structural shape, and structural level, are summarized in this paper from theoretical analyses and experimental data.

摘要

超疏水材料因其独特的表面润湿特性,可用于各个领域以优化生产和生活。然而,在一定压力和扰动条件下,沉积在超疏水材料上的液滴容易从Cassie状态转变为Wenzel状态,这限制了该材料的实际应用。近年来,大量研究工作探讨了超疏水表面在一系列外部环境下发生的润湿转变的转变行为、转变机理及影响因素。基于这些工作,本文系统总结了在促进材料表面润湿转变的外部条件(包括压力、冲击、蒸发、振动和电润湿)下,Cassie状态破坏的现象和动力学行为以及润湿转变的机理。此外,超疏水表面形态已被证明直接影响Cassie状态的持续时间。基于已发表的工作,本文从理论分析和实验数据两方面总结了特定形态对Cassie状态的影响,包括结构尺寸、结构形状和结构层次。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6a65/10933658/86146b02e90e/ADVS-11-2305961-g006.jpg

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