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基于碳的纳米材料在废水处理和生物气强化中的应用:最新综述。

Utilization of carbon-based nanomaterials for wastewater treatment and biogas enhancement: A state-of-the-art review.

作者信息

François Mathurin, Lin Kuen-Song, Rachmadona Nova, Khoo Kuan Shiong

机构信息

Department of Chemical Engineering and Materials Science/Environmental Technology Research Center, Yuan Ze University, Chung-Li District, Taoyuan City, 32003, Taiwan; Environmental Technology Research Center, Yuan Ze University, Chung-Li District, Taoyuan City, 32003, Taiwan.

Department of Chemical Engineering and Materials Science/Environmental Technology Research Center, Yuan Ze University, Chung-Li District, Taoyuan City, 32003, Taiwan; Environmental Technology Research Center, Yuan Ze University, Chung-Li District, Taoyuan City, 32003, Taiwan.

出版信息

Chemosphere. 2024 Feb;350:141008. doi: 10.1016/j.chemosphere.2023.141008. Epub 2023 Dec 26.

Abstract

The management of environmental pollution and carbon dioxide (CO) emissions is a challenge that has spurred increased research interest in determining sustainable alternatives to decrease biowaste. This state-of-the-art review aimed to describe the preparation and utilization of carbon-based nanomaterials (CNM) for biogas enhancement and wastewater contaminant (dyes, color, and dust particles) removal. The novelty of this review is that we elucidated that the performance of CNMs in the anaerobic digestion (AD) varies from one system to another. In addition, this review revealed that increasing the pyrolysis temperature can facilitate the transition from one CNM type to another and outlined the methods that can be used to develop CNMs, including arc discharge, chemical exfoliation, and laser ablation. In addition, this study showed that methane (CH) yield can be slightly increased (e.g. from 33.6% to 60.89%) depending on certain CNM factors, including its type, concentration, and feedstock. Temperature is a fundamental factor involved in the method and carbon sources used for CNM synthesis. This review determined that graphene oxide is not a good additive for biogas and CH yield improvement compared with other types of CNM, such as graphene and carbon nanotubes. The efficacy of CNMs in wastewater treatment depends on the temperature and pH of the solution. Therefore, CNMs are good adsorbents for wastewater contaminant removal and are a promising alternative for CO emissions reduction. Further research is necessary to determine the relationship between CNM synthesis and preparation costs while accounting for other factors such as gas flow, feedstock, consumption time, and energy consumption.

摘要

环境污染和二氧化碳(CO)排放的管理是一项挑战,这激发了人们对确定可持续替代方案以减少生物废弃物的研究兴趣。本综述旨在描述碳基纳米材料(CNM)在提高沼气产量和去除废水污染物(染料、颜色和灰尘颗粒)方面的制备和应用。本综述的新颖之处在于,我们阐明了CNM在厌氧消化(AD)中的性能因系统而异。此外,本综述还揭示,提高热解温度可促进从一种CNM类型向另一种类型的转变,并概述了可用于开发CNM的方法,包括电弧放电、化学剥离和激光烧蚀。此外,本研究表明,根据某些CNM因素,包括其类型、浓度和原料,甲烷(CH)产量可略有提高(例如从33.6%提高到60.89%)。温度是CNM合成方法和所用碳源中涉及的一个基本因素。本综述确定,与石墨烯和碳纳米管等其他类型的CNM相比,氧化石墨烯不是提高沼气和CH产量的良好添加剂。CNM在废水处理中的功效取决于溶液的温度和pH值。因此,CNM是去除废水污染物的良好吸附剂,也是减少CO排放的有前途的替代方案。有必要进行进一步研究,以确定CNM合成与制备成本之间的关系,同时考虑气流、原料、消耗时间和能源消耗等其他因素。

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