由4,5-二己基硫代邻苯二甲腈制备的酞菁，一种常用的结构单元。

Topkaya Derya, Şahin Zeynel, Işci Ümit, Dumoulin Fabienne

Department of Chemistry, Faculty of Sciences, Dokuz Eylül University, İzmir, Turkiye.

Department of Metallurgical & Materials Engineering, Faculty of Technology, Marmara University, İstanbul, Turkiye.

Turk J Chem. 2023 Oct 3;47(5):814-836. doi: 10.55730/1300-0527.3582. eCollection 2023.

Phthalocyanines are tetrapyrrolic artificial porphyrinoids that play major roles in advanced biological and technological applications. Research on this family of dyes is particularly active in Türkiye, with many derivatives being prepared from 4,5-dihexylthiophthalonitrile , which is one of the most popular noncommercially available building blocks for phthalocyanines. This review summarizes the phthalocyanines and their versatile properties and applications that have been published since 1994, when the synthesis of was first described, to emphasize the importance of this building block in plentiful applications, all with biomedical or technological impact.

酞菁是四吡咯类人工卟啉化合物，在先进的生物和技术应用中发挥着重要作用。在土耳其，对这类染料的研究特别活跃，许多衍生物是由4,5-二己基硫代邻苯二甲腈制备的，4,5-二己基硫代邻苯二甲腈是酞菁最常用的非商业可用构建单元之一。本综述总结了自1994年首次描述其合成以来已发表的酞菁及其多样的性质和应用，以强调这种构建单元在众多具有生物医学或技术影响的应用中的重要性。