• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

由4,5-二己基硫代邻苯二甲腈制备的酞菁,一种常用的结构单元。

Phthalocyanines prepared from 4,5-dihexylthiophthalonitrile, a popular building block.

作者信息

Topkaya Derya, Şahin Zeynel, Işci Ümit, Dumoulin Fabienne

机构信息

Department of Chemistry, Faculty of Sciences, Dokuz Eylül University, İzmir, Turkiye.

Department of Metallurgical & Materials Engineering, Faculty of Technology, Marmara University, İstanbul, Turkiye.

出版信息

Turk J Chem. 2023 Oct 3;47(5):814-836. doi: 10.55730/1300-0527.3582. eCollection 2023.

DOI:10.55730/1300-0527.3582
PMID:38173733
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10760877/
Abstract

Phthalocyanines are tetrapyrrolic artificial porphyrinoids that play major roles in advanced biological and technological applications. Research on this family of dyes is particularly active in Türkiye, with many derivatives being prepared from 4,5-dihexylthiophthalonitrile , which is one of the most popular noncommercially available building blocks for phthalocyanines. This review summarizes the phthalocyanines and their versatile properties and applications that have been published since 1994, when the synthesis of was first described, to emphasize the importance of this building block in plentiful applications, all with biomedical or technological impact.

摘要

酞菁是四吡咯类人工卟啉化合物,在先进的生物和技术应用中发挥着重要作用。在土耳其,对这类染料的研究特别活跃,许多衍生物是由4,5-二己基硫代邻苯二甲腈制备的,4,5-二己基硫代邻苯二甲腈是酞菁最常用的非商业可用构建单元之一。本综述总结了自1994年首次描述其合成以来已发表的酞菁及其多样的性质和应用,以强调这种构建单元在众多具有生物医学或技术影响的应用中的重要性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/5d78bffb5840/turkjchem-47-5-814f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/8ce2ae3f4425/turkjchem-47-5-814f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/5f602a8c95ba/turkjchem-47-5-814f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/4542f2681554/turkjchem-47-5-814f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/ff627208b543/turkjchem-47-5-814f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/ca5d471aae0d/turkjchem-47-5-814f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/4a657ce21bb7/turkjchem-47-5-814f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/bb923dee316d/turkjchem-47-5-814f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/3214fdc91d93/turkjchem-47-5-814f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/15f48783f44c/turkjchem-47-5-814f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/ad50a93930cd/turkjchem-47-5-814f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/c3efb7699303/turkjchem-47-5-814f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/6c1c902206b8/turkjchem-47-5-814f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/5d78bffb5840/turkjchem-47-5-814f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/8ce2ae3f4425/turkjchem-47-5-814f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/5f602a8c95ba/turkjchem-47-5-814f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/4542f2681554/turkjchem-47-5-814f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/ff627208b543/turkjchem-47-5-814f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/ca5d471aae0d/turkjchem-47-5-814f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/4a657ce21bb7/turkjchem-47-5-814f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/bb923dee316d/turkjchem-47-5-814f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/3214fdc91d93/turkjchem-47-5-814f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/15f48783f44c/turkjchem-47-5-814f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/ad50a93930cd/turkjchem-47-5-814f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/c3efb7699303/turkjchem-47-5-814f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/6c1c902206b8/turkjchem-47-5-814f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4548/10760877/5d78bffb5840/turkjchem-47-5-814f13.jpg

相似文献

1
Phthalocyanines prepared from 4,5-dihexylthiophthalonitrile, a popular building block.由4,5-二己基硫代邻苯二甲腈制备的酞菁,一种常用的结构单元。
Turk J Chem. 2023 Oct 3;47(5):814-836. doi: 10.55730/1300-0527.3582. eCollection 2023.
2
Synthesis and characterization of monoisomeric 1,8,15,22-substituted (A3B and A2B2) phthalocyanines and phthalocyanine-fullerene dyads.单异质 1,8,15,22-取代(A3B 和 A2B2)酞菁和酞菁-富勒烯偶联物的合成与表征。
J Org Chem. 2010 Aug 6;75(15):5178-94. doi: 10.1021/jo100766h.
3
Design and synthesis of novel phthalocyanines as potential antioxidant and antitumor agents starting with new synthesized phthalonitrile derivatives.以新合成的邻苯二甲腈衍生物为起始原料,设计并合成新型酞菁作为潜在的抗氧化剂和抗肿瘤剂。
RSC Adv. 2021 Oct 22;11(54):34300-34308. doi: 10.1039/d1ra05249g. eCollection 2021 Oct 18.
4
Complementary Syntheses Giving Access to a Full Suite of Differentially Substituted Phthalocyanine-Porphyrin Hybrids.互补合成法获得全系列取代位置不同的酞菁-卟啉杂化物。
Angew Chem Int Ed Engl. 2021 Mar 29;60(14):7632-7636. doi: 10.1002/anie.202016596. Epub 2021 Mar 1.
5
Synthesis and application of trifluoroethoxy-substituted phthalocyanines and subphthalocyanines.三氟乙氧基取代酞菁及亚酞菁的合成与应用
Beilstein J Org Chem. 2017 Oct 27;13:2273-2296. doi: 10.3762/bjoc.13.224. eCollection 2017.
6
Ultrasound versus Light: Exploring Photophysicochemical and Sonochemical Properties of Phthalocyanine-Based Therapeutics, Theoretical Study, and In Vitro Evaluations.超声与光:探索基于酞菁的治疗剂的光物理化学和声化学性质、理论研究及体外评估
ACS Appl Bio Mater. 2022 Mar 21;5(3):1139-1150. doi: 10.1021/acsabm.1c01199. Epub 2022 Mar 3.
7
Aldehyde Substituted Phthalocyanines: Synthesis, Characterization and Investigation of Photophysical and Photochemical Properties.醛取代酞菁:合成、表征及光物理和光化学性质研究
J Fluoresc. 2016 Jul;26(4):1521-34. doi: 10.1007/s10895-016-1852-x. Epub 2016 Jun 13.
8
Properties of some alkyl substituted phthalocyanines and related macrocycles.一些烷基取代酞菁及相关大环化合物的性质
Chem Rec. 2002;2(4):225-36. doi: 10.1002/tcr.10028.
9
Functional Supramolecular Gels Based on the Hierarchical Assembly of Porphyrins and Phthalocyanines.基于卟啉和酞菁分级组装的功能性超分子凝胶
Front Chem. 2019 May 15;7:336. doi: 10.3389/fchem.2019.00336. eCollection 2019.
10
Synthesis and Characterization of New Zinc Phthalocyanine - Dodecenyl Succinic Anhydride Benzoic Groups.新型锌酞菁-十二碳烯基琥珀酸酐苯甲酸基团的合成与表征
Curr Org Synth. 2020;17(6):488-495. doi: 10.2174/1570179417666200519091950.

本文引用的文献

1
Far-red triplet sensitized -to- photoswitching of azobenzene in bioplastics.远红光三重态敏化生物塑料中偶氮苯的光开关效应
Chem Sci. 2022 Sep 14;13(40):11904-11911. doi: 10.1039/d2sc04230d. eCollection 2022 Oct 19.
2
Recent Advances in Phthalocyanine and Porphyrin-Based Materials as Active Layers for Nitric Oxide Chemical Sensors.酞菁和卟啉基材料在作为活性层的用于一氧化氮化学传感器方面的最新进展。
Sensors (Basel). 2022 Jan 24;22(3):895. doi: 10.3390/s22030895.
3
Phthalocyanines: An Old Dog Can Still Have New (Photo)Tricks!酞菁:老狗也能有新(光)招!
Molecules. 2021 May 10;26(9):2823. doi: 10.3390/molecules26092823.
4
Site-selective formation of an iron(iv)-oxo species at the more electron-rich iron atom of heteroleptic μ-nitrido diiron phthalocyanines.在杂配体μ-氮化物二铁酞菁中电子密度更高的铁原子上进行位点选择性形成铁(IV)-氧物种。
Chem Sci. 2015 Aug 1;6(8):5063-5075. doi: 10.1039/c5sc01811k. Epub 2015 Jun 16.
5
Effect of the Substitution Pattern (Peripheral vs Non-Peripheral) on the Spectroscopic, Electrochemical, and Magnetic Properties of Octahexylsulfanyl Copper Phthalocyanines.取代模式(外围与非外围)对辛基硫代酞菁铜的光谱、电化学和磁学性质的影响。
Inorg Chem. 2018 Jun 4;57(11):6456-6465. doi: 10.1021/acs.inorgchem.8b00528. Epub 2018 May 16.
6
Solution-processed single crystal microsheets of a novel dimeric phthalocyanine-involved triple-decker for high-performance ambipolar organic field effect transistors.用于高性能双极性有机场效应晶体管的新型含二聚酞菁三层结构的溶液法处理单晶微片。
Chem Commun (Camb). 2017 Nov 28;53(95):12754-12757. doi: 10.1039/c7cc06797f.
7
Porphyrinoids for Chemical Sensor Applications.卟啉类化合物在化学传感器中的应用。
Chem Rev. 2017 Feb 22;117(4):2517-2583. doi: 10.1021/acs.chemrev.6b00361. Epub 2016 Oct 19.
8
Fluorescent H-aggregates of an asymmetrically substituted mono-amino Zn(ii) phthalocyanine.一种不对称取代的单氨基锌(II)酞菁的荧光H聚集体。
Dalton Trans. 2017 Feb 14;46(6):1914-1926. doi: 10.1039/c6dt02651f.
9
Synthesis of an ABCD-Type Phthalocyanine by Intramolecular Cyclization Reaction.通过分子内环化反应合成 ABCD 型酞菁。
Org Lett. 2016 Jul 1;18(13):3234-7. doi: 10.1021/acs.orglett.6b01489. Epub 2016 Jun 16.
10
The optical characterization of metal-mediated aggregation behaviour of amphiphilic Zn(ii) phthalocyanines.两亲性锌(II)酞菁金属介导聚集行为的光学表征
Phys Chem Chem Phys. 2016 Jun 21;18(23):15574-83. doi: 10.1039/c6cp01093h. Epub 2016 May 25.