Contaminant degradation by •OH during sediment oxygenation: Effect of abundant solid matrix in aquifer.

Aquifer oxygenation for hydroxyl radical (•OH) production has been recently proposed as a promising strategy for in-situ remediation. However, the high performance of this process was justified at low solid-to-liquid ratios (SLRs) of suspension systems. It remains unclear whether and how the performance is affected by abundant solid matrixes. Here we assessed the influence of SLR on •OH production and contaminant degradation during sediment oxygenation. Cumulative •OH increased from 21.8 to 165.2 μM when the SLR increased from 200 to 1600 g/L, while phenol degradation increased with the increase in SRL at the values lower than 1200 g/L and decreased at higher SLRs. As the main sediment component, silica exhibited a negligible effect on •OH production and phenol degradation because of the weak adsorption towards aqueous Fe(II). Whereas, the other component, alumina, significantly inhibited •OH production and phenol degradation because it strongly adsorbed Fe(II). •OH scavenging by solid reactive matrixes was mainly responsible for the inhibition at high SLRs. The scavenging effect could be mitigated by mediating the main reactive Fe(II) species from solid-adsorbed to dissolved phase with ligand addition. Our findings are important for understanding the side reactions and optimizing the remediation performance during aquifer oxygenation.