Ponomarenko Artem D, Nikulova Uliana V, Shapagin Aleksey V
Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences (IPCE RAS), 31, bld.4 Leninsky Prospect, Moscow 119071, Russia.
Polymers (Basel). 2023 Dec 30;16(1):130. doi: 10.3390/polym16010130.
Phase equilibria, interdiffusion and structure in the initial uncured mixtures of epoxy oligomer-polysulfone-alkyl glycidyl ether were studied. Binodal curves were constructed on isothermal sections of the ternary phase diagram. Thermodynamic mixing parameters were calculated and spinodal curves were plotted. The interdiffusion coefficients of components, establishing the technological modes of mixing the components, were determined. To validate the phase diagram, the phase structure of mixtures, the composition of which at a temperature of 40 °C corresponds to heterogeneous and homogeneous regions, was studied.
研究了环氧低聚物-聚砜-烷基缩水甘油醚初始未固化混合物中的相平衡、互扩散和结构。在三元相图的等温截面上构建了双节线曲线。计算了热力学混合参数并绘制了旋节线曲线。确定了建立组分混合工艺模式的组分互扩散系数。为了验证相图,研究了温度为40℃时其组成对应于非均相和均相区域的混合物的相结构。