Nassereddine Yassine, Benyoussef Manal, Asbani Bouchra, El Marssi Mimoun, Jouiad Mustapha
Laboratory of Physics of Condensed Matter, University of Picardie Jules Verne, Scientific Pole, 33 Rue Saint-Leu, CEDEX 1, 80039 Amiens, France.
Nanomaterials (Basel). 2023 Dec 23;14(1):51. doi: 10.3390/nano14010051.
Owing to their remarkable success in photocatalytic applications, multiferroic BiFeO and its derivatives have gained a highly promising position as electrode materials for future developments of efficient catalysts. In addition to their appropriate band gaps, these materials exhibit inherent intrinsic polarizations enabling efficient charge carrier separation and their high mobility without the need for additional co-catalysts. Here, we review the existing strategies for enhancing the photocatalytic performances of BiFeO-based materials and we describe the physico-chemical properties at the origin of their exceptional photocatalytic behavior. A special focus is paid to the degradation of organic pollutants and water splitting, both driven through photocatalysis to unveil the correlation between BiFeO size, substitution, and doping on the one hand and the photocatalytic performances on the other hand. Finally, we provide practical recommendations for future developments of high-performing BiFeO-based electrodes.
由于多铁性BiFeO及其衍生物在光催化应用中取得了显著成功,它们作为高效催化剂未来发展的电极材料已占据了极具前景的地位。除了具有合适的带隙外,这些材料还表现出固有的本征极化,能够实现有效的电荷载流子分离,并且具有高迁移率,无需额外的助催化剂。在此,我们综述了提高BiFeO基材料光催化性能的现有策略,并描述了其卓越光催化行为背后的物理化学性质。特别关注通过光催化驱动的有机污染物降解和水分解,以揭示BiFeO尺寸、取代和掺杂一方面与光催化性能另一方面之间的相关性。最后,我们为高性能BiFeO基电极的未来发展提供了实用建议。