Carrasco-Quiroz Marioli, Martínez-Gil Ana María, Nevares Ignacio, Del Alamo-Sanza Maria
Department of Analytical Chemistry, UVaMOX-Universidad de Valladolid, 34004 Palencia, Spain.
Department of Agroforestry Engineering, UVaMOX-Universidad de Valladolid, 34004 Palencia, Spain.
Molecules. 2023 Dec 31;29(1):231. doi: 10.3390/molecules29010231.
The design, construction and validation of a device for the accurate measurement of the dissolved oxygen content in wine and simultaneously the variation of its spectral fingerprint is presented. The novelty of this system is due to two innovative approaches. First, robustness in measurements is obtained by using cuvettes designed to simultaneously measure the dissolved oxygen and color. Secondly, automatic monitoring is performed to ensure that measurements are always taken at the same cuvette position. The fine-tuning of the device with the study of white and red wines makes it possible, on the one hand, to establish the appropriate measurement conditions and, on the other hand, to determine the amount of oxygen required to cause specific changes in the wine spectrum, information that could not be obtained until now. The preliminary results are very interesting, presenting precise data on the amount of oxygen consumed by the wine and the variations in its visible spectrum, thus reflecting the modification of the responsible phenolic compounds. This information is of great interest, since it helps to optimize the handling of the wine and, if necessary, to moderate the uptake of oxygen in each type of wine to ensure the maintenance of the color during the winemaking and conservation processes of each type of wine. The results of the experiments indicate that this new instrument is feasible and accurate for detecting oxygen changes during wine production.
介绍了一种用于精确测量葡萄酒中溶解氧含量并同时测量其光谱指纹变化的装置的设计、构建和验证。该系统的新颖之处在于两种创新方法。首先,通过使用设计用于同时测量溶解氧和颜色的比色皿来获得测量的稳健性。其次,进行自动监测以确保始终在相同的比色皿位置进行测量。通过对白葡萄酒和红葡萄酒的研究对该装置进行微调,一方面可以确定合适的测量条件,另一方面可以确定导致葡萄酒光谱发生特定变化所需的氧量,而这些信息在此之前是无法获得的。初步结果非常有趣,给出了葡萄酒消耗的氧量及其可见光谱变化的精确数据,从而反映了相关酚类化合物的变化。这些信息非常重要,因为它有助于优化葡萄酒的处理,并在必要时控制每种葡萄酒的氧气吸收量,以确保在每种葡萄酒的酿造和保存过程中保持其颜色。实验结果表明,这种新仪器对于检测葡萄酒生产过程中的氧气变化是可行且准确的。