Zheng Xinbing, Long Wei, Zhu Changshun, Zhao Longbin, Hu Xinbin, Liu Sheng, Jiang Wenming, Peng Yaxiong
School of Materials and Chemical Engineering, Hubei University of Technology, Wuhan 430068, China.
Key Laboratory of Green Materials for Light Industry of Hubei Provincial, Wuhan 430068, China.
Materials (Basel). 2023 Dec 28;17(1):182. doi: 10.3390/ma17010182.
Dual-scale (nano and micron) particle-reinforced TiB/6061Al matrix composites with different contents of TiB were prepared using powder metallurgy, and then analyzed via microstructure observation and tests of microhardness, tensile properties, and friction and wear properties. The 6061Al powders' particles changed from spherical to flaky after two rounds of high-energy ball milling, and the TiB enhancer was embedded in or wrapped by the matrix particles after high-energy ball milling. Metallurgical bonding between TiB particles and the matrix was achieved, and AlTi was synthesized in situ during sintering. The hot-pressing process eliminated the internal defects of the composites, and the TiB particles were diffusely distributed in the matrix. The best comprehensive mechanical properties (hardness and tensile strength) were achieved when the mass fraction of TiB was 5% (1% micron + 4% nano); the hardness and tensile strength of the composites reached 131 HV and 221 MPa-79.5% and 93.9% higher than those of the pure matrix, respectively. The composites' average coefficient of friction and volumetric wear rate were reduced. Composites with a TiB mass fraction of 7% (3% micron + 4% nano) had the highest average coefficients of friction and the lowest volumetric wear rate of 0.402 and 0.216 mm∙N∙m, respectively. It was observed that adhesion influences the friction mechanism, which transitions from adhesive wear with slight oxidative wear to abrasive wear.
采用粉末冶金法制备了不同TiB含量的双尺度(纳米和微米)颗粒增强TiB/6061Al基复合材料,然后通过微观结构观察以及显微硬度、拉伸性能和摩擦磨损性能测试对其进行分析。经过两轮高能球磨后,6061Al粉末颗粒从球形变为片状,高能球磨后TiB增强相被嵌入基体颗粒中或被基体颗粒包裹。实现了TiB颗粒与基体之间的冶金结合,并且在烧结过程中原位合成了AlTi。热压工艺消除了复合材料的内部缺陷,TiB颗粒在基体中呈弥散分布。当TiB的质量分数为5%(1%微米+4%纳米)时,复合材料获得了最佳综合力学性能(硬度和拉伸强度);复合材料的硬度和拉伸强度分别达到131 HV和221 MPa,比纯基体分别提高了79.5%和93.9%。复合材料的平均摩擦系数和体积磨损率降低。TiB质量分数为7%(3%微米+4%纳米)的复合材料具有最高的平均摩擦系数,体积磨损率最低,分别为0.402和0.216 mm∙N∙m。观察发现,粘着作用影响摩擦机制,摩擦机制从轻微氧化磨损的粘着磨损转变为磨粒磨损。