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选择性激光熔化制备的微米级TiB/AlZnMgCu(Sc,Zr)复合材料的微观结构、力学性能及断裂行为

Microstructure, Mechanical Properties and Fracture Behavior of Micron-Sized TiB/AlZnMgCu(Sc,Zr) Composites Fabricated by Selective Laser Melting.

作者信息

Yin Peng, Liu Yantao, Liang Zhuoheng, Pan Wei, Shao Shuobing, Zhang Yongzhong

机构信息

National Engineering & Technology Research Center for Non-Ferrous Metals Composites, GRINM Group Corporation Limited, Beijing 101407, China.

Grinm Metal Composites Technology Co., Ltd., Beijing 101407, China.

出版信息

Materials (Basel). 2023 Mar 6;16(5):2112. doi: 10.3390/ma16052112.

Abstract

In this paper, micron-sized TiB/AlZnMgCu(Sc,Zr) composites were fabricated by selective laser melting (SLM) using directly mixed powder. Nearly fully dense (over 99.5%) and crack-free SLM-fabricated TiB/AlZnMgCu(Sc,Zr) composite samples were obtained and its microstructure and mechanical properties were investigated. It is found that the laser absorption rate of powder is improved by introducing micron-sizedTiB particles, then the energy density required for SLM forming can be reduced, and the densification can finally be improved. Some crystalline TiB formed a coherent relationship with the matrix, while some broken TiB particles did not, however, MgZn and Al(Sc,Zr) can perform as intermediate phases to connect these non-coherent surfaces to aluminum matrix. All these factors lead to an increase in strength of the composite. The SLM-fabricated micron-sized TiB/AlZnMgCu(Sc,Zr) composite finally shows a very high ultimate tensile strength of ~646 MPa and yield strength of ~623 MPa, which are higher than many other aluminum composites fabricated by SLM, while maintaining a relatively good ductility of ~4.5%. The fracture of TiB/AlZnMgCu(Sc,Zr) composite is occurred along the TiB particles and the bottom of the molten pool. This is due to the concentration of stress from the sharp tip of TiB particles and the coarse precipitated phase at the bottom of the molten pool. The results show that TiB plays a positive role in AlZnMgCu alloys fabricated by SLM, but finer TiB particles should be studied.

摘要

在本文中,通过选择性激光熔化(SLM)使用直接混合粉末制备了微米级TiB/AlZnMgCu(Sc,Zr)复合材料。获得了近全致密(超过99.5%)且无裂纹的SLM制备的TiB/AlZnMgCu(Sc,Zr)复合材料样品,并对其微观结构和力学性能进行了研究。研究发现,引入微米级TiB颗粒可提高粉末的激光吸收率,进而降低SLM成型所需的能量密度,并最终提高致密化程度。一些结晶态的TiB与基体形成了共格关系,而一些破碎的TiB颗粒则没有,不过,MgZn和Al(Sc,Zr)可作为中间相将这些非共格表面与铝基体连接起来。所有这些因素导致复合材料强度增加。SLM制备的微米级TiB/AlZnMgCu(Sc,Zr)复合材料最终表现出非常高的极限抗拉强度,约为646MPa,屈服强度约为623MPa,高于许多其他通过SLM制备的铝基复合材料,同时保持了约4.5%的相对良好的延展性。TiB/AlZnMgCu(Sc,Zr)复合材料的断裂沿着TiB颗粒和熔池底部发生。这是由于TiB颗粒尖锐尖端和熔池底部粗大析出相的应力集中所致。结果表明,TiB在通过SLM制备的AlZnMgCu合金中起到了积极作用,但应研究更细的TiB颗粒。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76af/10003815/f0e487ec43f0/materials-16-02112-g002.jpg

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