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通过锈改性预腐蚀处理加速耐候钢的稳定化

Accelerating stabilization of weathering steel through rust modification pre-corrosion treatment.

作者信息

Hu Qiang, Yang Shanwu, Zhang Xu, Da Guangjie, Zhang Wenhua

机构信息

Collaborative Innovation Center of Steel Technology, University of Science and Technology Beijing, Beijing, 100083, China.

Research Institute of Technology, Shougang Group Co., Ltd., Beijing, 100043, China.

出版信息

Heliyon. 2023 Dec 16;10(1):e23842. doi: 10.1016/j.heliyon.2023.e23842. eCollection 2024 Jan 15.

Abstract

To accelerate the formation of the protective rust layer on weathering steel, a new pre-corrosion method containing a replacement reaction was explored. This process was mixed with Cu in the pre-corrosion rust layer to imitate the enrichment of alloying elements through long-term corrosion. By using various analysis methods, the initial corrosion behavior of weathering steel and carbon steel with/without pre-corrosion treatment was studied under indoor wet-dry cycle conditions. The results showed that the pre-corrosion treatment covers the steel surface with a rust layer containing high-concentration Cu. Subsequently, the corrosion uniformity of the weathering steel was significantly improved, and the protective performance of corrosion products was enhanced due to the high concentration of Cu enrichment. This technology is expected to provide a new way to perfect the service performance of weathering steel at the initial stage of application.

摘要

为加速耐候钢表面保护性锈层的形成,探索了一种包含置换反应的新型预腐蚀方法。该工艺在预腐蚀锈层中混入铜,以模拟长期腐蚀过程中合金元素的富集。通过多种分析方法,研究了经过/未经过预腐蚀处理的耐候钢和碳钢在室内干湿循环条件下的初始腐蚀行为。结果表明,预腐蚀处理在钢表面形成了富含高浓度铜的锈层。随后,耐候钢的腐蚀均匀性显著提高,由于高浓度铜的富集,腐蚀产物的保护性能增强。该技术有望为在应用初期完善耐候钢的服役性能提供一种新途径。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/58a6/10777024/5a8a7b1dd2dd/ga1.jpg

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