Huang Zekun, Feng Liping, Xia Xianjie, Zhao Jing, Qi Penglu, Wang Yiting, Zhou Junhua, Shen Laifa, Zhang Shengliang, Zhang Xiaogang
State Key Laboratory of Mechanics and Control for Aerospace Structures, Nanjing University of Aeronautics and Astronautics, No. 29 Yudao Street, Nanjing 210016, China.
Jiangsu Key Laboratory of Electrochemical Energy Storage Technologies, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China.
Nanoscale. 2024 Feb 1;16(5):2078-2096. doi: 10.1039/d3nr05461f.
Electrochromic materials and devices with the capability of dynamic optical regulation have attracted considerable attention recently and have shown a variety of potential applications including energy-efficient smart windows, multicolor displays, atuto-diming mirrors, military camouflage, and adaptive thermal management due to the advantages of active control, wide wavelength modulation, and low energy consumption. However, its development still experiences a number of issues such as long response time and inadequate durability. Nanostructuring has demonstrated that it is an effective strategy to improve the electrochromic performance of the materials due to the increased reaction active sites and the reduced ion diffusion distance. Various advanced inorganic nanomaterials with high electrochromic performance have been developed recently, significantly contributing to the development of electrochromic applications. In this review, we systematically introduce and discuss the recent advances in advanced inorganic nanomaterials including zero-, one-, and two-dimensional materials for high-performance electrochromic applications. Finally, we outline the current major challenges and our perspectives for the future development of nanostructured electrochromic materials and applications.
具有动态光学调节能力的电致变色材料和器件近年来备受关注,由于其具有主动控制、宽波长调制和低能耗等优点,已展现出包括节能智能窗、多色显示器、自动调光后视镜、军事伪装和自适应热管理等多种潜在应用。然而,其发展仍面临一些问题,如响应时间长和耐久性不足。纳米结构化已证明,由于反应活性位点增加和离子扩散距离减小,这是提高材料电致变色性能的有效策略。近年来已开发出各种具有高电致变色性能的先进无机纳米材料,为电致变色应用的发展做出了重大贡献。在本综述中,我们系统地介绍和讨论了用于高性能电致变色应用的先进无机纳米材料的最新进展,包括零维、一维和二维材料。最后,我们概述了纳米结构化电致变色材料及应用当前面临的主要挑战以及对其未来发展的展望。