Chen Jian, Song Ge, Cong Shan, Zhao Zhigang
School of Nano-Tech and Nano-Bionics, University of Science and Technology of China, Hefei, 230026, China.
Key Lab of Nanodevices and Applications, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou, 215123, China.
Adv Mater. 2023 Nov;35(47):e2300179. doi: 10.1002/adma.202300179. Epub 2023 Oct 15.
With rapid advances in optoelectronics, electrochromic materials and devices have received tremendous attentions from both industry and academia for their strong potentials in wearable and portable electronics, displays/billboards, adaptive camouflage, tunable optics, and intelligent devices, etc. However, conventional electrochromic materials and devices typically present some serious limitations such as undesirable dull colors, and long switching time, hindering their deeper development. Optical resonators have been proven to be the most powerful platform for providing strong optical confinement and controllable lightmatter interactions. They generate locally enhanced electromagnetic near-fields that can convert small refractive index changes in electrochromic materials into high-contrast color variations, enabling multicolor or even panchromatic tuning of electrochromic materials. Here, resonant-cavity-enhanced electrochromic materials and devices, an advanced and emerging trend in electrochromics, are reviewed. In this review, w e will focus on the progress in multicolor electrochromic materials and devices based on different types of optical resonators and their advanced and emerging applications, including multichromatic displays, adaptive visible camouflage, visualized energy storage, and applications of multispectral tunability. Among these topics, principles of optical resonators, related materials/devices and multicolor electrochromic properties are comprehensively discussed and summarized. Finally, the challenges and prospects for resonant-cavity-enhanced electrochromic materials and devices are presented.
随着光电子学的飞速发展,电致变色材料及器件因其在可穿戴和便携式电子设备、显示器/广告牌、自适应伪装、可调谐光学器件以及智能设备等方面的巨大潜力,受到了工业界和学术界的广泛关注。然而,传统的电致变色材料及器件通常存在一些严重的局限性,如颜色暗淡、响应时间长等,这阻碍了它们的进一步发展。光学谐振器已被证明是提供强光学限制和可控光与物质相互作用的最强大平台。它们能产生局部增强的电磁近场,可将电致变色材料中的微小折射率变化转化为高对比度的颜色变化,从而实现电致变色材料的多色甚至全色调谐。在此,对谐振腔增强型电致变色材料及器件这一电致变色领域的先进且新兴的趋势进行综述。在本综述中,我们将重点关注基于不同类型光学谐振器的多色电致变色材料及器件的进展及其先进和新兴应用,包括多色显示器、自适应可见光伪装、可视化能量存储以及多光谱可调谐性的应用。在这些主题中,将对光学谐振器的原理、相关材料/器件以及多色电致变色特性进行全面讨论和总结。最后,介绍了谐振腔增强型电致变色材料及器件面临的挑战和前景。