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钙浸渍麻风树碳(Ca-Enc)的合成、表征及其除氟能力评估

Synthesis, characterization, and evaluation of fluoride removal capacity of calcium-impregnated Euphorbia neriifolia carbon (Ca-Enc).

作者信息

Subramanium Rajkumar, Sathiyamoorthi Ezhaveni, Rajagopal Saravanakumar, Krishnamoorthy Rajavenkatesh, Lee Jintae, A Lakshman Kumar

机构信息

Department of Chemistry, SRM Madurai College for Engineering and Technology, Pottapalayam, Sivagangai, 630612, Tamil Nadu, India.

School of Chemical Engineering, Yeungnam University, Gyeongsan, 38541, Republic of Korea.

出版信息

Environ Sci Pollut Res Int. 2024 Jan 20. doi: 10.1007/s11356-024-31943-9.

Abstract

Fluoride ions must be removed from drinking water in order to prevent fluorosis. Many conventional techniques have been examined for the defluoridation of water all over the world. As far as fluoride ions are concerned, adsorption is the most promising method for the removal of them from aqueous environments. In the present study, we aim to find out how well Euphorbia neriifolia plants can remove fluoride from water using activated and carbonized adsorbents. The Euphorbia neriifolia plant stem was pulverized, dried, and activated using calcium ions extracted from used eggshells collected nearby. The synthesized adsorbent material before and after adsorption of fluoride ions was systematically characterized using FTIR, XRD, SEM with EDAX, TGA, and zero-point charge. The defluoridation capacity of the as-prepared adsorbent material was investigated using batch adsorption studies. Various influencing factors such as contact time, solution pH, initial fluoride concentration, mass of the adsorbent, temperature, and co-existing ions were systematically investigated towards the removal of fluoride ion on prepared adsorbent material. This study was conducted to identify the optimal conditions of prepared adsorbent for the maximum removal of fluoride ions from aqueous solution. A groundwater sample with fluoride content of more than 1.5 ppm was taken and studied in this present work. A basic quality indicator of the synthesized material was examined, and its ability to remove fluoride was determined. The findings provide insight into the selective elimination of fluoride ions from aqueous environment.

摘要

必须从饮用水中去除氟离子以预防氟中毒。世界各地已经研究了许多用于水脱氟的传统技术。就氟离子而言,吸附是从水环境中去除它们最有前景的方法。在本研究中,我们旨在了解霸王鞭植物使用活化和碳化吸附剂从水中去除氟的效果如何。将霸王鞭植物茎粉碎、干燥,并使用从附近收集的用过的蛋壳中提取的钙离子进行活化。使用傅里叶变换红外光谱(FTIR)、X射线衍射(XRD)、带有能谱仪的扫描电子显微镜(SEM)、热重分析(TGA)和零电荷点对吸附氟离子前后的合成吸附剂材料进行系统表征。使用批量吸附研究来研究所制备吸附剂材料的脱氟能力。系统研究了接触时间、溶液pH值、初始氟浓度、吸附剂质量、温度和共存离子等各种影响因素对所制备吸附剂材料去除氟离子的作用。进行这项研究是为了确定所制备吸附剂从水溶液中最大程度去除氟离子的最佳条件。在本研究中采集并研究了氟含量超过1.5 ppm的地下水样品。检测了合成材料的基本质量指标,并确定了其去除氟的能力。这些发现为从水环境中选择性去除氟离子提供了见解。

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