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用传统环氧树脂和可持续树脂制备的亚麻增强聚合物的静态和冲击性能

Static and Impact Properties of Flax-Reinforced Polymers Prepared with Conventional Epoxy and Sustainable Resins.

作者信息

Ciardiello Raffaele, Benelli Alessandro, Paolino Davide Salvatore

机构信息

Department of Mechanical and Aerospace Engineering, Politecnico di Torino, 10129 Turin, Italy.

Inter-Departmental Multi-Disciplinary Research Centre J-TECH @PoliTO, 10129 Turin, Italy.

出版信息

Polymers (Basel). 2024 Jan 8;16(2):190. doi: 10.3390/polym16020190.

Abstract

The study assessed the tensile, flexural, and impact properties of composite materials reinforced with flax fibers, employing three distinct resin types. The composite laminates were fabricated using three commercial resins: a conventional epoxy resin, an epoxy resin with a 31% weight concentration of bio-renewable content, and a recyclable methyl methacrylate infusion resin. This aims to assess if there exists a commercially available alternative to the traditional epoxy resin that can reduce the overall carbon footprint of composite materials. To investigate the influence of humidity on the mechanical behavior of the flax layers, a drying treatment was applied to the fibers before the infusion process. Micro-computed tomography analysis revealed that heat treatment resulted in a reduction of porosity, although it did not affect the mechanical response of the composite laminates. Moreover, laminates produced with non-recyclable and sustainable resins exhibited no significant change in tensile and flexural modulus. In contrast, those produced with recyclable resin demonstrated a slight reduction in the strengths of the composite laminates. Conversely, out-of-plane impact tests and repeated impact tests indicated that composites prepared with recyclable and bio-epoxy resin formulations present superior damage resistance to repeated impact compared to traditional epoxy resin.

摘要

该研究评估了采用三种不同树脂类型的亚麻纤维增强复合材料的拉伸、弯曲和冲击性能。复合层压板使用三种商业树脂制成:一种传统环氧树脂、一种生物可再生含量重量浓度为31%的环氧树脂以及一种可回收的甲基丙烯酸甲酯灌注树脂。这旨在评估是否存在一种可替代传统环氧树脂的商业可用材料,以减少复合材料的总体碳足迹。为了研究湿度对亚麻层机械性能的影响,在灌注过程之前对纤维进行了干燥处理。微观计算机断层扫描分析表明,热处理导致孔隙率降低,尽管它并未影响复合层压板的机械响应。此外,用不可回收和可持续树脂生产的层压板在拉伸和弯曲模量方面没有显著变化。相比之下,用可回收树脂生产的层压板在复合层压板强度方面略有降低。相反,平面外冲击试验和反复冲击试验表明,与传统环氧树脂相比,用可回收和生物环氧树脂配方制备的复合材料对反复冲击具有更好的抗损伤性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0453/10820720/fb3ebde8aa22/polymers-16-00190-g001.jpg

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