具有吡唑烷-3-酮核心的茉莉酰-L-异亮氨酸类似物的简便模块化合成。
Facile modular synthesis of jasmonoyl-l-isoleucine analogs possessing a pyrazolidin-3-one core.
作者信息
Vizcaíno Páez Samuel, Durango Diego, Müller Christian Jürgen, Breuning Matthias, Fletcher Wiston Quiñones
机构信息
Química Orgánica de Productos Naturales, Universidad de Antioquia Medellín 050010 Antioquia Colombia
Química de los Productos Naturales y los Alimentos, Universidad Nacional de Colombia Medellín 050034 Antioquia Colombia.
出版信息
RSC Adv. 2024 Jan 25;14(6):3790-3797. doi: 10.1039/d3ra07887f. eCollection 2024 Jan 23.
A short and flexible route to pyrazolidin-3-one analogs of the phytohormone (+)-7-iso-jasmonoyl-l-isoleucine is presented. The compounds were assembled from four basic building blocks, namely a pyrazolidin-3-one core, alkyl chain, linker and amino ester or acid. The efficacy of this approach was demonstrated in the synthesis of 11 analogs with variations in all parts of the molecule.
本文介绍了一种简洁灵活的方法来合成植物激素(+)-7-异茉莉酰-L-异亮氨酸的吡唑啉-3-酮类似物。这些化合物由四个基本结构单元组装而成，即吡唑啉-3-酮核心、烷基链、连接基和氨基酯或酸。该方法在合成11种分子各部分均有变化的类似物中得到了验证。
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