Leontiadis Konstantinos, Theodoratou Katerina, Tsioptsias Costas, Tsivintzelis Ioannis
Department of Chemical Engineering, Aristotle University of Thessaloniki, University Campus, 54124 Thessaloniki, Greece.
Department of Chemical Engineering, University of Western Macedonia, 50132 Kozani, Greece.
Nanomaterials (Basel). 2024 Jan 19;14(2):223. doi: 10.3390/nano14020223.
In this study, the mechanical properties and thermal stability of composite polypropylene (PP) drawn fibers with two different organically modified montmorillonites were experimentally investigated and optimized using a response surface methodology. Specifically, the Box-Behnken Design of Experiments method was used in order to investigate the effect of the filler content, the compatibilizer content, and the drawing temperature on the tensile strength and the onset decomposition temperature of the PP composite drawn fibers. The materials were characterized by tensile tests, thermogravimetry, and X-ray diffraction. Two types of composites were investigated with the only difference being the type of filler, namely, Cloisite 10A or Cloisite 15A. In both cases, statistically significant models were obtained regarding the effect of design variables on tensile strength, while poor significance was observed for the onset decomposition temperature. Nanocomposite fibers with tensile strength up to 540 MPa were obtained. Among the design variables, the drawing temperature exhibited the most notable effect on tensile strength, while the effect of both clays was not significant.
在本研究中,使用响应面方法对含有两种不同有机改性蒙脱土的复合聚丙烯(PP)拉伸纤维的力学性能和热稳定性进行了实验研究并进行了优化。具体而言,采用Box-Behnken实验设计方法来研究填料含量、增容剂含量和拉伸温度对PP复合拉伸纤维的拉伸强度和起始分解温度的影响。通过拉伸试验、热重分析和X射线衍射对材料进行了表征。研究了两种类型的复合材料,唯一的区别在于填料的类型,即Cloisite 10A或Cloisite 15A。在这两种情况下,均获得了关于设计变量对拉伸强度影响的具有统计学意义的模型,而对于起始分解温度则观察到显著性较差。获得了拉伸强度高达540 MPa的纳米复合纤维。在设计变量中,拉伸温度对拉伸强度的影响最为显著,而两种黏土的影响均不显著。