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胶辅助合成与表征CoAgFeO:对结构、磁性、光学和生物医学性质的洞察

Gum-Assisted Synthesis and Characterization of CoAgFeO: Insight into Structural, Magnetic, Optical, and Biomedical Properties.

作者信息

Tamboli Qudsiya Y, Patange Sunil M, Mohanta Yugal Kishore, Patil Asha D, Ali Rizwan, Bushnak Ibraheem, Zakde Kranti

机构信息

Department of Basic and Applied Science, MGM University, Aurangabad 431001, Maharashtra, India.

Materials Science Research Laboratory, SKM, Gunjoti, Osmanabad 413613, Maharashtra, India.

出版信息

ACS Omega. 2024 Jan 8;9(3):3835-3845. doi: 10.1021/acsomega.3c06578. eCollection 2024 Jan 23.

Abstract

The sol-gel method was employed to prepare nano CoFeO and silver-substituted CoFeO nanohybrids (CoAgFeO, = 0, 0.1, 0.2, 0.3, 0.4) utilizing gum as biofuel. The morphology, size, shape, magnetic, optical, and functional groups of the crystallites were determined using various techniques such as UV-visible, Fourier transform infrared, X-ray diffraction, Rietveld, scanning electron microscopy, transmission electron microscopy, vibrating sample magnetometry, and photoluminescence. The produced nanoferrite has a spherical shape with cubic spinal structures. The optical properties were investigated in two different bands in the photoluminescence emission spectra at 469 and 493 nm. Saturation magnetization (Ms) and coercivity (Hc) decrease as the Ag content increases significantly. Furthermore, antibacterial (Gram-positive bacteria bacterial strains, and , and Gram-negative bacterial strains, , and ), antibiofilm activity (), and antioxidant (DPPH) activities were investigated. The substantial increase in the silver content offers a constructive impact on studied biomedical activities. These findings encourage additional research into the use of hybrid nanoparticles (an amalgamation of ferrite and a noble metal) in biomedical and pharmaceutical applications.

摘要

采用溶胶-凝胶法,以阿拉伯胶为生物燃料制备了纳米CoFeO以及银取代的CoFeO纳米杂化物(CoAgFeO,x = 0、0.1、0.2、0.3、0.4)。利用紫外可见光谱、傅里叶变换红外光谱、X射线衍射、Rietveld精修、扫描电子显微镜、透射电子显微镜、振动样品磁强计和光致发光等多种技术,对微晶的形态、尺寸、形状、磁性、光学性质和官能团进行了测定。所制备的纳米铁氧体具有立方尖晶石结构的球形形状。在光致发光发射光谱的469和493 nm两个不同波段研究了光学性质。随着银含量的显著增加,饱和磁化强度(Ms)和矫顽力(Hc)降低。此外,还研究了抗菌活性(革兰氏阳性细菌菌株枯草芽孢杆菌和金黄色葡萄球菌,以及革兰氏阴性细菌菌株大肠杆菌、铜绿假单胞菌)、抗生物膜活性(铜绿假单胞菌)和抗氧化(DPPH)活性。银含量的大幅增加对所研究的生物医学活性产生了积极影响。这些发现促使人们进一步研究杂化纳米粒子(铁氧体与贵金属的混合物)在生物医学和制药应用中的用途。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5b2b/10809381/5d41ba2cc7ba/ao3c06578_0001.jpg

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