Grelska Joanna
A. Chełkowski Institute of Physics, University of Silesia in Katowice, 75 Pułku Piechoty 1, 41-500 Chorzów, Poland.
Phys Chem Chem Phys. 2024 Feb 7;26(6):5713-5716. doi: 10.1039/d3cp05269a.
In the article published by Jukić [I. Jukić , , 2021, , 19537], the authors discovered a specific lifetime distribution of hydrogen bonds in some pure hydrogen-bonding liquids. The distribution derived by computer simulations in the range of 0-0.15 ps consists of three characteristic peaks. They call the first maximum the 'dimer peak', the second the 'cluster peak', and the third the 'topology peak'. In the article in question, mostly linear- and circular-cluster-forming mono-ols were simulated to show that the third peak is universal in these H-bonding substances. Moreover, the topology of the clusters, which was wrongly assumed to be detected in the tertiary lifetime peak, is instead seen in the distribution of the first maximum.
在朱基奇发表的文章[I. 朱基奇，，2021，，19537]中，作者发现了一些纯氢键液体中氢键的特定寿命分布。通过计算机模拟得出的0 - 0.15皮秒范围内的分布由三个特征峰组成。他们将第一个最大值称为“二聚体峰”，第二个称为“簇峰”，第三个称为“拓扑峰”。在上述文章中，主要对形成线性和环状簇的一元醇进行了模拟，以表明第三个峰在这些氢键物质中是普遍存在的。此外，曾被错误地认为在三级寿命峰中检测到的簇的拓扑结构，实际上出现在第一个最大值的分布中。
