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用于精确检测果蔬提取物中甲醛的绿色纳米传感器。

Green nanosensor for precise detection of formaldehyde in fruits and vegetables extract.

机构信息

Division of Agricultural Physics, ICAR-Indian Agricultural Research Institute, New Delhi 110012, India.

Division of Agricultural Physics, ICAR-Indian Agricultural Research Institute, New Delhi 110012, India.

出版信息

Food Chem. 2024 Jun 15;443:138520. doi: 10.1016/j.foodchem.2024.138520. Epub 2024 Jan 23.

Abstract

Present study reports fabrication of a low cost and eco-friendly formaldehyde nanosensor based on green magnetite nanoparticles synthesized using Mango (Mangifera indica L.) tree leaves extract. The formaldehyde is found in air, water and food. When inhaled or consumed formaldehyde has carcinogenic effects on human health. In this study the cyclic voltammetry technique was used to characterize the performance of the nanosensor. The green nanosensor fabricated in this study, to detect formaldehyde, demonstrated good sensitivity (193.4 µA mg Lcm) in linearity range 0.03-0.5 mg/L with low threshold detection limit (0.05 mg/L). The green nanosensor also showed shelf life of four weeks without considerable change in the initial peak oxidation current. The real sample analysis was performed in various fruits and vegetables (Litchi chinensis, Syzygium cumini, Solanum lycopersicum and Cucumis sativus). The recovery rates were more than 93 % in sample extracts for formaldehyde detection. The comparison of the nanosensor for detection of formaldehyde with the colorimetric sensor revealed that the green nanosensor reproducibility (RSD = 1.8 %) is better than colorimetric sensor (RSD = 3.23 %). The results from the comparative studies of green nanosensor with colorimetric sensor established the potential of the green nanosensor as a forefront technology for futuristic smart detection of formaldehyde.

摘要

本研究报告采用绿色磁铁矿纳米粒子合成方法,以芒果(Mangifera indica L.)树叶提取物为原料,制备了一种低成本、环保的甲醛纳米传感器。甲醛存在于空气、水和食物中。吸入或摄入甲醛会对人类健康产生致癌作用。在这项研究中,循环伏安技术用于表征纳米传感器的性能。本研究制备的绿色纳米传感器用于检测甲醛,在 0.03-0.5mg/L 的线性范围内具有良好的灵敏度(193.4 µA mg Lcm),检测下限低(0.05mg/L)。绿色纳米传感器还表现出四周的保质期,初始氧化峰电流没有明显变化。在各种水果和蔬菜(荔枝、蒲桃、番茄和黄瓜)中进行了实际样品分析。对于甲醛检测,样品提取物的回收率均高于 93%。将纳米传感器用于检测甲醛与比色传感器进行比较的结果表明,绿色纳米传感器的重现性(RSD=1.8%)优于比色传感器(RSD=3.23%)。绿色纳米传感器与比色传感器的比较研究结果表明,绿色纳米传感器作为未来智能甲醛检测的前沿技术具有潜力。

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