同型配合物双（吗啉）氯化金（I）和双（吗啉）溴化金（I）的晶体结构
Crystal structures of the isotypic complexes bis-(morpholine)-gold(I) chloride and bis-(morpholine)-gold(I) bromide.
作者信息
Döring Cindy, Jones Peter G
机构信息
Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Hagenring 30, D-38106 Braunschweig, Germany.
出版信息
Acta Crystallogr E Crystallogr Commun. 2023 Nov 16;79(Pt 12):1161-1165. doi: 10.1107/S2056989023009702. eCollection 2023 Dec 1.
The compounds bis-(morpholine-κ)gold(I) chloride, [Au(CHNO)]Cl, , and bis-(morpholine-κ)gold(I) bromide, [Au(CHNO)]Br, , crystallize isotypically in space group 2/ with = 4. The gold atoms, which are axially positioned at the morpholine rings, lie on inversion centres (so that the N-Au-N coordination is exactly linear) and the halide anions on twofold axes. The residues are connected by a classical hydrogen bond N-H⋯halide and by a short gold⋯halide contact to form a layer structure parallel to the plane. The morpholine oxygen atom is not involved in classical hydrogen bonding.
二（吗啉-κ）金（I）氯化物，[Au(CHNO)]Cl，以及二（吗啉-κ）金（I）溴化物，[Au(CHNO)]Br，以同晶型方式结晶于空间群2/，Z = 4。轴向位于吗啉环上的金原子位于反演中心（使得N-Au-N配位恰好呈线性），卤化物阴离子位于二重轴上。这些残基通过经典的N-H⋯卤化物氢键以及短的金⋯卤化物接触相连，形成平行于bc平面的层状结构。吗啉氧原子不参与经典氢键作用。
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