Department Chemie, Technische Universität München, Lichtenbergstreet 4, 85747 Garching b. M., Germany.
Chem Soc Rev. 2012 Jan 7;41(1):370-412. doi: 10.1039/c1cs15182g. Epub 2011 Aug 24.
Recently accumulated experimental evidence for aurophilic interactions in and between molecular gold(I) compounds and the results of pertinent theoretical calculations are reviewed for the period from 2007 to mid-2011. The influence of the intra- and intermolecular bonding contacts between the closed-shell metal centres, Au-Au, on the molecular and crystal structures, and the consequences of these effects for the chemical and physical properties of gold compounds are summarized for the various classes of mono- and polynuclear systems. The literature survey builds on the contents of previous reviews and relates new experimental and theoretical findings to earlier observations (353 references).
从 2007 年到 2011 年年中，对金（I）化合物分子内和分子间的金-金亲合作用的实验证据进行了综述，并对相关的理论计算结果进行了综述。总结了各种单核和多核体系中，闭壳金属中心（Au-Au）之间的分子内和分子间键合接触对分子和晶体结构的影响，以及这些效应对金化合物化学和物理性质的影响。本文献综述是在前几次综述的基础上，将新的实验和理论发现与早期的观察结果联系起来（引用 353 篇文献）。
