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用于传感和多催化氢化反应的剥离型MXene-AuNPs杂化物

Exfoliated MXene-AuNPs hybrid in sensing and multiple catalytic hydrogenation reactions.

作者信息

Kumar Yogesh, Thomas Tijin, Pérez-Tijerina E, Bogireddy N K R, Agarwal V

机构信息

Investigation Center for Engineering and Applied Sciences (CIICAp-IICBA), Autonomous State University of Morelos (UAEM), Av. Univ. 1001, Col. Chamilpa, Cuernavaca 62209 Mor., Mexico.

Faculty of Physics and Mathematics (FCFM-UANL), Autonomous University of Nuevo Leon, Cd. Universitaria, San Nicolás de los Garza, N.L. 66451, Mexico.

出版信息

Nanotechnology. 2024 Feb 27;35(20). doi: 10.1088/1361-6528/ad26da.

DOI:10.1088/1361-6528/ad26da
PMID:38320322
Abstract

The increasing use of nanomaterials in consumer products is expected to lead to environmental contamination sometime soon. As water pollution is a pressing issue that threatens human survival and impedes the promotion of human health, the search for adsorbents for removing newly identified contaminants from water has become a topic of intensive research. The challenges in the recyclability of contaminated water continue to campaign the development of highly reusable catalysts. Although exfoliated 2D MXene sheets have demonstrated the capability towards water purification, a significant challenge for removing some toxic organic molecules remains a challenge due to a need for metal-based catalytic properties owing to their rapid response. In the present study, we demonstrate the formation of hybrid structure AuNPs@MXene (MoCT) during the sensitive detection of Au nanoparticle through MXene sheets without any surface modification, and subsequently its applications as an efficient catalyst for the degradation of 4-nitrophenol (4-NP), methyl orange (MO), and methylene blue (MB). The hybrid structure (AuNPs@MXene) reveals remarkable reusability for up to eight consecutive cycles, with minimal reduction in catalytic efficiency and comparable apparent reaction rate constant () values for 4-NP, MB, and MO, compared to other catalysts reported in the literature.

摘要

纳米材料在消费品中的使用日益增加,预计不久后将导致环境污染。由于水污染是一个紧迫的问题,威胁着人类生存并阻碍人类健康的提升,寻找用于去除水中新发现污染物的吸附剂已成为一个深入研究的课题。受污染水的可循环利用方面的挑战持续推动着高可重复使用催化剂的发展。尽管剥落的二维MXene片已展现出净水能力,但由于其快速响应需要基于金属的催化特性,去除某些有毒有机分子仍是一个重大挑战。在本研究中,我们展示了在通过MXene片对金纳米颗粒进行灵敏检测的过程中,无需任何表面修饰即可形成杂化结构AuNPs@MXene(MoCT),随后其作为降解4-硝基苯酚(4-NP)、甲基橙(MO)和亚甲基蓝(MB)的高效催化剂的应用。与文献中报道的其他催化剂相比,杂化结构(AuNPs@MXene)显示出高达连续八个循环的显著可重复使用性,催化效率降低最小,且4-NP、MB和MO的表观反应速率常数()值相当。

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ACS Omega. 2024 Jul 25;9(31):33335-33350. doi: 10.1021/acsomega.4c04185. eCollection 2024 Aug 6.