Yamamoto Masanori, Goto Shunsuke, Tang Rui, Yamazaki Kaoru
Department of Chemical Science and Engineering, Tokyo Institute of Technology Ookayama 2-12-1 Meguro Tokyo 152-8550 Japan
Institute of Multidisciplinary Research for Advanced Materials, Tohoku University 2-1-1 Katahira, Aoba Sendai 980-8577 Japan.
Chem Sci. 2023 Dec 26;15(6):1953-1965. doi: 10.1039/d3sc05022j. eCollection 2024 Feb 7.
Precise template synthesis will realize three-dimensionally ordered nanoporous graphenes (NPGs) with a spatially controlled seamless graphene structure and fewer edges. These structural features result in superelastic nature, high electrochemical stability, high electrical conductivity, and fast diffusion of gases and ions at the same time. Such innovative 3D graphene materials are conducive to solving energy-related issues for a better future. To further improve the attractive properties of NPGs, we review the template synthesis and its mechanism by chemical vapor deposition of hydrocarbons, analysis of the nanoporous graphene structure, and applications in electrochemical and mechanical devices.
精确的模板合成将实现具有空间可控无缝石墨烯结构且边缘较少的三维有序纳米多孔石墨烯（NPG）。这些结构特征同时导致了超弹性、高电化学稳定性、高导电性以及气体和离子的快速扩散。这种创新的三维石墨烯材料有助于解决与能源相关的问题，以创造更美好的未来。为了进一步提升NPG的诱人性能，我们综述了通过碳氢化合物化学气相沉积进行的模板合成及其机理、纳米多孔石墨烯结构分析以及在电化学和机械设备中的应用。
