Bücker Anna, Gehlhaar Alexander, Wölper Christoph, Schulz Stephan
Institute of Inorganic Chemistry, University of Duisburg-Essen, Essen 45117, Germany.
Center for Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen, Duisburg 47057, Germany.
Chem Commun (Camb). 2024 Mar 7;60(21):2902-2905. doi: 10.1039/d3cc06223f.
The electron-rich germylene LGa(μ-Cl)GeAr (1) (L = CH[C(Me)N(Dipp)], Dipp = 2,6-PrCH, Ar = 2,6-MesCH, Mes = 2,4,6-MeCH) shows promising potential in the σ-bond activation of unpolar molecules as is shown in oxidative addition reactions with H and P, yielding L(Cl)GaGe(H)Ar (2) and L(Cl)Ga(P)GeAr (3). Compounds 2 and 3 were characterised spectroscopically (H, C{H}, (P{H}), IR) and by single-crystal X-ray diffraction (sc-XRD).
富电子的亚锗烯LGa(μ-Cl)GeAr (1)（L = CH[C(Me)N(Dipp)]，Dipp = 2,6-PrCH，Ar = 2,6-MesCH，Mes = 2,4,6-MeCH）在非极性分子的σ键活化方面显示出有前景的潜力，如在与H和P的氧化加成反应中所示，生成L(Cl)GaGe(H)Ar (2)和L(Cl)Ga(P)GeAr (3)。化合物2和3通过光谱（H、C{H}、(P{H})、IR）和单晶X射线衍射（sc-XRD）进行了表征。
