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CdAlO/CdO 纳米复合材料:绿茶提取物介导的溶胶-凝胶自燃烧合成、表征及作为潜在储氢材料的研究。

CdAlO/CdO nanocomposites: green tea extract-mediated sol-gel auto-combustion synthesis, characterization, and study as a potential hydrogen storage material.

机构信息

Research Center for Environmental Determinants of Health (RCEDH), Health Institute, Kermanshah University of Medical Sciences, Kermanshah, Iran.

Department of Environmental Health Engineering, Faculty of Health, Kermanshah University of Medical Sciences, Kermanshah, Iran.

出版信息

Environ Sci Pollut Res Int. 2024 Mar;31(14):21370-21379. doi: 10.1007/s11356-024-32527-3. Epub 2024 Feb 23.

DOI:10.1007/s11356-024-32527-3
PMID:38388980
Abstract

In this article, we present the synthesis of binary CdAlO/CdO nanocomposites using green tea extracts and green chemistry methods for high-performance hydrogen storage. The green tea extract contains bioactive compounds (polyphenols) that act as reducing agents, which facilitate the reaction between metal ions and water. By examining the structural and morphological characteristics of the obtained substrates using scanning electron microscopy (SEM), X-ray diffraction (XRD), transmission electron microscopy (TEM), and Fourier transform infrared spectroscopy (FT-IR), it was demonstrated that the nanocomposites were successfully synthesized. We evaluated the electrochemical performance of the synthesized CdAlO/CdO nanocomposites using a three-electrode chronopotentiometry system. According to the results, the synthesized nanocomposites are capable of storing 1750 mAh/g of hydrogen at a constant current of 1 Amp. By using green tea extract as a natural structure-directing agent, the CdAlO/CdO nanocomposite can be developed more sustainably as high-performance hydrogen storage materials. Ultimately, this work contributes to the advancement of sustainable energy storage through the synthesis of a promising new material.

摘要

本文采用绿茶提取物和绿色化学方法合成了二元 CdAlO/CdO 纳米复合材料,用于高性能储氢。绿茶提取物中含有生物活性化合物(多酚),可作为还原剂,促进金属离子与水的反应。通过扫描电子显微镜(SEM)、X 射线衍射(XRD)、透射电子显微镜(TEM)和傅里叶变换红外光谱(FT-IR)研究了所获得的基底的结构和形态特征,证明纳米复合材料已成功合成。我们使用三电极恒电流计时电位系统评估了合成的 CdAlO/CdO 纳米复合材料的电化学性能。结果表明,在 1Amp 的恒定电流下,合成的纳米复合材料能够储存 1750mAh/g 的氢气。通过使用绿茶提取物作为天然结构导向剂,CdAlO/CdO 纳米复合材料可以作为高性能储氢材料得到更可持续的发展。最终,这项工作通过合成一种有前途的新材料为可持续能源存储的发展做出了贡献。

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