Dash Zane S, Huang Raymond Q, Kimber Ana N, Olubajo Opeyemi T, Polk Mark, Rancu Oliver P, Zhang Lauren L, Fu Jane, Nagelj Nejc, Reynolds Kristopher G, Zheng Shao Liang, Dogutan Dilek K
Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA.
Acta Crystallogr C Struct Chem. 2024 Mar 1;80(Pt 3):85-90. doi: 10.1107/S2053229624001621. Epub 2024 Feb 26.
The compound [5,10,15,20-tetrakis(4-fluoro-2,6-dimethylphenyl)porphyrinato]platinum(II), [Pt(CHFN)] or Pt(II)TFP, has been synthesized and structurally characterized by single-crystal X-ray crystallography. The Pt porphyrin exhibits a long-lived phosphorescent excited state (τ = 66 µs), which has been characterized by transient absorption and emission spectroscopy. The phosphorescence is extremely sensitive to oxygen, as reflected by a quenching rate constant of 5.0 × 10 M s, and as measured by Stern-Volmer quenching analysis.
化合物[5,10,15,20-四(4-氟-2,6-二甲基苯基)卟啉铂(II)]，即[Pt(CHFN)]或铂(II)TFP，已通过单晶X射线晶体学进行了合成和结构表征。该铂卟啉表现出长寿命的磷光激发态（τ = 66 μs），这已通过瞬态吸收和发射光谱进行了表征。磷光对氧气极其敏感，通过猝灭速率常数5.0×10 M s反映出来，并通过斯特恩-沃尔默猝灭分析进行测量。
