• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

硼基化合物、它们的化合物及反应活性：结构与键合视角

Boryls, their compounds and reactivity: a structure and bonding perspective.

作者信息

Guo Xueying, Lin Zhenyang

机构信息

Department of Chemistry, The Hong Kong University of Science and Technology Clear Water Bay Kowloon Hong Kong

出版信息

Chem Sci. 2024 Feb 1;15(9):3060-3070. doi: 10.1039/d3sc06864a. eCollection 2024 Feb 28.

DOI:10.1039/d3sc06864a
PMID:38425516
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10901493/
Abstract

Boryls and their compounds are important due to their diverse range of applications in the fields of materials science and catalysis. They are an integral part of boron chemistry, which has attracted tremendous research interest over the past few decades. In this perspective, we provide an in-depth analysis of the reaction chemistry of boryl compounds from a structure and bonding perspective. We discuss the reactivity of boryls in various transition metal complexes and diborane(4) compounds towards different substrate molecules, with a focus on their nucleophilic and electrophilic properties in various reaction processes. Additionally, we briefly discuss the reactivity of boryl radicals. Our analysis sheds new light on the unique properties of boryls and their potential for catalytic applications.

摘要

硼基及其化合物因其在材料科学和催化领域的广泛应用而显得重要。它们是硼化学的重要组成部分，在过去几十年中引起了极大的研究兴趣。从这个角度出发，我们从结构和键合的角度对硼基化合物的反应化学进行了深入分析。我们讨论了硼基在各种过渡金属配合物和二硼烷（4）化合物中对不同底物分子的反应活性，重点关注它们在各种反应过程中的亲核和亲电性质。此外，我们还简要讨论了硼基自由基的反应活性。我们的分析为硼基的独特性质及其催化应用潜力提供了新的见解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c867/10901493/03cfa9559fe0/d3sc06864a-s3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c867/10901493/a27765fb4f60/d3sc06864a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c867/10901493/fdca052eba22/d3sc06864a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c867/10901493/c993e004a68d/d3sc06864a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c867/10901493/f1f72597d6ee/d3sc06864a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c867/10901493/4c08cab39ee6/d3sc06864a-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c867/10901493/8f65ea658360/d3sc06864a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c867/10901493/441c714a83ce/d3sc06864a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c867/10901493/1a5dc3bee0d1/d3sc06864a-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c867/10901493/03cfa9559fe0/d3sc06864a-s3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c867/10901493/a27765fb4f60/d3sc06864a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c867/10901493/fdca052eba22/d3sc06864a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c867/10901493/c993e004a68d/d3sc06864a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c867/10901493/f1f72597d6ee/d3sc06864a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c867/10901493/4c08cab39ee6/d3sc06864a-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c867/10901493/8f65ea658360/d3sc06864a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c867/10901493/441c714a83ce/d3sc06864a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c867/10901493/1a5dc3bee0d1/d3sc06864a-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c867/10901493/03cfa9559fe0/d3sc06864a-s3.jpg

相似文献

1
Boryls, their compounds and reactivity: a structure and bonding perspective.硼基化合物、它们的化合物及反应活性：结构与键合视角
Chem Sci. 2024 Feb 1;15(9):3060-3070. doi: 10.1039/d3sc06864a. eCollection 2024 Feb 28.
2
Mapping the Electronic Structure and the Reactivity Trends for Stabilized α-Boryl Carbanions.绘制稳定α-硼基碳负离子的电子结构和反应活性趋势图。
Chemistry. 2021 Aug 25;27(48):12352-12361. doi: 10.1002/chem.202101464. Epub 2021 Jul 24.
3
EPR studies of the generation, structure, and reactivity of n-heterocyclic carbene borane radicals.EPR 研究氮杂环卡宾硼烷自由基的生成、结构和反应性。
J Am Chem Soc. 2010 Feb 24;132(7):2350-8. doi: 10.1021/ja909502q.
4
Lewis Base-Boryl Radicals Enabled Borylation Reactions and Selective Activation of Carbon-Heteroatom Bonds.路易斯碱-硼基自由基促进了硼化反应和碳杂原子键的选择性活化。
Acc Chem Res. 2023 Jan 17;56(2):169-186. doi: 10.1021/acs.accounts.2c00752. Epub 2022 Dec 26.
5
Electrophilicity and Nucleophilicity of Boryl Radicals.硼自由基的亲电性和亲核性。
J Org Chem. 2017 Mar 17;82(6):2898-2905. doi: 10.1021/acs.joc.6b02849. Epub 2017 Mar 2.
6
Carbene Radicals in Transition-Metal-Catalyzed Reactions.过渡金属催化反应中的卡宾自由基
ACS Catal. 2023 Apr 6;13(8):5428-5448. doi: 10.1021/acscatal.3c00591. eCollection 2023 Apr 21.
7
Easy access to nucleophilic boron through diborane to magnesium boryl metathesis.通过二硼烷到镁硼基复分解反应，容易获得亲核硼。
Nat Commun. 2017 Apr 7;8:15022. doi: 10.1038/ncomms15022.
8
Enabling Nucleophilic Reactivity in High-Spin Fe(II) Imido Complexes: From Elementary Steps to Cooperative Catalysis.在高自旋Fe(II)亚胺配合物中实现亲核反应活性：从基本步骤到协同催化
Acc Chem Res. 2023 Dec 5;56(23):3392-3403. doi: 10.1021/acs.accounts.3c00511. Epub 2023 Nov 13.
9
Boronyl chemistry: the BO group as a new ligand in gas-phase clusters and synthetic compounds.硼酰基化学：BO 基团作为气相团簇和合成化合物中的一种新型配体。
Acc Chem Res. 2014 Aug 19;47(8):2435-45. doi: 10.1021/ar500136j. Epub 2014 Jun 10.
10
Boron(II) Cations: Interplay between Lewis-Pair-Acceptor and Electron-Donor Properties.硼（II）阳离子：路易斯对受体与电子供体性质之间的相互作用
Angew Chem Int Ed Engl. 2018 Aug 27;57(35):11456-11459. doi: 10.1002/anie.201806135. Epub 2018 Jul 31.

引用本文的文献

1
A zinc boryl compound unlocks diverse reactivity pathways beyond nucleophilic borylation.一种锌硼基化合物开启了超越亲核硼化的多种反应途径。
Nat Commun. 2025 Jul 10;16(1):6349. doi: 10.1038/s41467-025-61062-z.
2
Breaking Bonds at Tin(II): Reductive or Oxidative Addition?锡（II）处的键断裂：还原加成还是氧化加成？
Angew Chem Int Ed Engl. 2025 Aug 4;64(32):e202503050. doi: 10.1002/anie.202503050. Epub 2025 Jun 12.
3
Desymmetrization of Diboron(4) by a Trifluorination B-Masking Strategy: Practical Synthesis of Unsymmetrical Diboron Species.

本文引用的文献

1
Boryl-substituted low-valent heavy group 14 compounds.硼基取代的低价重14族化合物。
Chem Soc Rev. 2024 Jan 2;53(1):361-379. doi: 10.1039/d3cs00791j.
2
Boryl radical catalysis enables asymmetric radical cycloisomerization reactions.硼基自由基催化可实现不对称自由基环异构化反应。
Science. 2023 Dec;382(6674):1056-1065. doi: 10.1126/science.adg1322. Epub 2023 Nov 30.
3
Reactions of Tetra(o-tolyl)diborane(4) with Organic Azides: Formation of Fluorescent Boron-Fused Hexazenes.四（邻甲苯基）二硼烷（4）与有机叠氮化物的反应：含硼稠合六氮烯的形成。
通过三氟化硼掩蔽策略实现二硼(4)的去对称化：不对称二硼物种的实用合成
J Org Chem. 2024 Aug 16;89(16):11753-11760. doi: 10.1021/acs.joc.4c00715. Epub 2024 Jul 31.
Chemistry. 2023 Sep 12;29(51):e202302027. doi: 10.1002/chem.202302027. Epub 2023 Aug 7.
4
Photoinduced Halogen-Atom Transfer by -Heterocyclic Carbene-Ligated Boryl Radicals for C(sp)-C(sp) Bond Formation.硼基自由基引发的偕杂环卡宾配体的卤原子转移反应构建 C(sp)-C(sp) 键。
J Am Chem Soc. 2023 Jan 18;145(2):991-999. doi: 10.1021/jacs.2c10444. Epub 2022 Dec 30.
5
Lewis Base-Boryl Radicals Enabled Borylation Reactions and Selective Activation of Carbon-Heteroatom Bonds.路易斯碱-硼基自由基促进了硼化反应和碳杂原子键的选择性活化。
Acc Chem Res. 2023 Jan 17;56(2):169-186. doi: 10.1021/acs.accounts.2c00752. Epub 2022 Dec 26.
6
Boryl Radicals Enabled a Three-Step Sequence to Assemble All-Carbon Quaternary Centers from Activated Trichloromethyl Groups.硼基自由基促进三步序列从三氯甲基活化基团构建全碳季碳中心。
J Am Chem Soc. 2022 Aug 24;144(33):15275-15285. doi: 10.1021/jacs.2c05798. Epub 2022 Aug 11.
7
Difluoromethylation of Unactivated Alkenes Using Freon-22 through Tertiary Amine-Borane-Triggered Halogen Atom Transfer.通过叔胺-硼烷引发的卤原子转移，使用氟利昂-22 对非活化烯烃进行二氟甲基化。
J Am Chem Soc. 2022 Aug 10;144(31):14288-14296. doi: 10.1021/jacs.2c05356. Epub 2022 Jul 27.
8
Application of the Spin-Center Shift in Organic Synthesis.自旋中心转移在有机合成中的应用。
JACS Au. 2022 Apr 11;2(5):1032-1042. doi: 10.1021/jacsau.2c00051. eCollection 2022 May 23.
9
Dehydroxylative Alkylation of α-Hydroxy Carboxylic Acid Derivatives via a Spin-Center Shift.通过自旋中心迁移实现 α-羟基羧酸衍生物的去羟烷基化反应。
Angew Chem Int Ed Engl. 2022 Jun 20;61(25):e202201329. doi: 10.1002/anie.202201329. Epub 2022 Apr 21.
10
Stereoselective hydrogen atom transfer to acyclic radicals: a switch enabling diastereodivergent borylative radical cascades.立体选择性氢原子转移至非环状自由基：一种可使非对映选择性硼化自由基级联反应发生转变的开关。
Nat Commun. 2022 Jan 20;13(1):426. doi: 10.1038/s41467-022-28071-8.