（2,2'-联吡啶-κ,')(4,4'-二甲氧基-2,2'-联吡啶-κ,')钯(II) 双（三氟甲磺酸酯）
(2,2'-Bi-pyridine-κ,')(4,4'-dimeth-oxy-2,2'-bipyridine-κ,')palladium(II) bis-(tri-fluoro-meth-anesulfonate).
作者信息
Vargas Brittney B, Arman Hadi D, Adrian Rafael A
机构信息
Department of Chemistry and Biochemistry, University of the Incarnate Word, San Antonio, Texas 78209, USA.
Department of Chemistry, The University of Texas at San Antonio, San Antonio, Texas 78249, USA.
出版信息
IUCrdata. 2024 Feb 8;9(Pt 2):x240109. doi: 10.1107/S2414314624001093. eCollection 2024 Feb.
In the title complex salt, Pd(CHN)(CHNO), the palladium(II) atom is fourfold coordinated by two chelating ligands, 2,2'-bi-pyridine and 4,4'-dimeth-oxy-2,2'-bi-pyridine, in a distorted square-planar environment. In the crystal, weak π-π stacking inter-actions between the 2,2'-bi-pyridine rings [centroid-to-centroid distances = 3.8984 (19) Å] and between the 4,4'-dimeth-oxy-2,2'-bi-pyridine rings [centroid-to-centroid distances = 3.747 (18) Å] contribute to the alignment of the complex cations in columns parallel to the -axis direction.
在标题配合物盐Pd(CHN)(CHNO)中，钯(II)原子在扭曲的平面正方形环境中由两个螯合配体2,2'-联吡啶和4,4'-二甲氧基-2,2'-联吡啶进行四重配位。在晶体中，2,2'-联吡啶环之间[质心到质心距离 = 3.8984 (19) Å]以及4,4'-二甲氧基-2,2'-联吡啶环之间[质心到质心距离 = 3.747 (18) Å]的弱π-π堆积相互作用有助于配合物阳离子在平行于c轴方向的列中排列。
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