Rani Diksha, Kumar Anil, Kumar Dinesh
Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology, Murthal, Sonepat, 131039, India.
Department of Chemistry, A. I. Jat. H. M. College, Rohtak, 124001, India.
J Fluoresc. 2025 Mar;35(3):1769-1780. doi: 10.1007/s10895-024-03628-6. Epub 2024 Mar 8.
Extensive investigations were conducted on the structural and photoluminescence characteristics of the present nanosamples, encompassing PL, TEM, PXRD, EDAX, CCT, and CIE research. PXRD studies established a single phase, and TEM instruments were used to examine the dimensions and topographical behavior. The EDAX analysis examined the magnitude of the different components that were present. Decay lifetimes, radiative and non-radiative energy transfer rates, and a number of intensity limitations have all been found using PL spectra. Two significant peaks were visible in the blue (B) and yellow (Y) regions of the photoluminescence (PL) spectra upon NUV excitation, at 486 nm and 577 nm. At 7 mol% Dy ions, the PL intensity peaked. After that, it began to decline as a result of the concentration quenching process brought on by multipolar exchanges (s = 4.1445). The values of 0.86423 ms, 81%, and 226 s were discovered to be the decay life time, non radiative rates, and quantum efficiency of the ideal powder, respectively. Further analysis of SrYDy(PO) nanocrystals revealed that their chromaticity coordinates (0.305, 0.321), and CCT value (6902 K) matched those of NTSE and commercial LEDs, certifying their use in innovative optoelectronic appliances, particularly single phased WLEDs.
对当前纳米样品的结构和光致发光特性进行了广泛研究,包括光致发光(PL)、透射电子显微镜(TEM)、粉末X射线衍射(PXRD)、能量色散X射线能谱(EDAX)、相关色温(CCT)和国际照明委员会(CIE)研究。PXRD研究确定为单相,使用TEM仪器检查尺寸和形貌行为。EDAX分析检测了存在的不同成分的含量。利用PL光谱发现了衰减寿命、辐射和非辐射能量转移率以及一些强度限制。在近紫外(NUV)激发下,光致发光(PL)光谱的蓝色(B)和黄色(Y)区域出现两个显著峰值,分别位于486 nm和577 nm处。在镝(Dy)离子含量为7 mol%时,PL强度达到峰值。此后,由于多极交换引起的浓度猝灭过程(s = 4.1445),PL强度开始下降。发现理想粉末的衰减寿命、非辐射率和量子效率的值分别为0.86423 ms、81%和226 s。对SrYDy(PO)纳米晶体的进一步分析表明,其色度坐标(0.305, 0.321)和CCT值(6902 K)与暖白色荧光灯(NTSE)和商用发光二极管(LED)相匹配,证明了它们在创新型光电器件中的应用,特别是在单相白光发光二极管(WLED)中的应用。