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用于增强白蜡木弯曲性能的三元低共熔溶剂研究

Study of ternary deep eutectic solvents to enhance the bending properties of ash wood.

作者信息

Bai Ruocai, Wang Wenhao, Chen Mengyao, Wu Yan

机构信息

College of Furnishings and Industrial Design, Nanjing Forestry University Nanjing 210037 China

Co-Innovation Center of Ecient Processing and Utilization of Forest Resources, Nanjing Forestry University Nanjing 210037 China.

出版信息

RSC Adv. 2024 Mar 8;14(12):8090-8099. doi: 10.1039/d4ra00357h. eCollection 2024 Mar 6.

Abstract

Deep eutectic solvents (DESs) are considered one of the most promising biomass pretreatment reagents, and their research applications in woody fibrous biomass are increasing yearly. Inspired by the research related to wood bending, we explored the effects of different DES systems on the bending development of wood, and the results showed that the addition of anhydrous ferric trichloride to the DES system of lactic acid/choline chloride could enhance the treatment effect that increased the bendability and torsion resistance of ash wood. The anhydrous FeCl could act as an active site and provide acidic protons to improve the treatment efficiency of DES. In addition, the addition of an appropriate amount of water can reduce the viscosity of the DES system, and the highest lignin removal rate was obtained at 10 wt% of water in the DES, which resulted in the best mechanical properties and tensile resilience of ash wood, with the tensile strength and stability of 97 MPa and 13.6%, respectively, as determined by experiments with different water contents in different mass fractions. Therefore, using a DES can effectively improve the bending properties of wood.

摘要

深共熔溶剂(DESs)被认为是最有前景的生物质预处理试剂之一,其在木质纤维生物质中的研究应用逐年增加。受木材弯曲相关研究的启发,我们探究了不同DES体系对木材弯曲性能的影响,结果表明,在乳酸/氯化胆碱的DES体系中添加无水三氯化铁可增强处理效果,提高白蜡木的弯曲性能和抗扭性。无水FeCl₃可作为活性位点并提供酸性质子,以提高DES的处理效率。此外,添加适量的水可降低DES体系的粘度,当DES中水的质量分数为10 wt%时,木质素去除率最高,此时白蜡木的力学性能和拉伸回弹性最佳,通过不同质量分数的不同含水量实验测定,其拉伸强度和稳定性分别为97 MPa和13.6%。因此,使用DES可有效改善木材的弯曲性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f090/10921390/7c0acd6a8006/d4ra00357h-f1.jpg

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