Kaneko Takumi, Yabushita Mizuho, Osuga Ryota, Sawada Yugo, Sato Kei, Liu Ben, Nakagawa Yoshinao, Nakajima Kiyotaka, Tomishige Keiichi
Department of Applied Chemistry, School of Engineering, Tohoku University, 6-6-07 Aoba, Aramaki, Aoba-ku, Sendai, Miyagi 980-8579, Japan.
Institute for Catalysis, Hokkaido University, Kita 21 Nishi 10, Kita-ku, Sapporo, Hokkaido 001-0021, Japan.
Chem Commun (Camb). 2024 Mar 28;60(27):3681-3684. doi: 10.1039/d4cc00186a.
Paired Ga sites represented by the Ga-O-Si-O-Ga sequence were firstly formed intentionally in CHA-type zeolite frameworks the transcription of pre-formed paired Ga species in a Ga-rich amorphous silica-gallia under seed-assisted hydrothermal conditions. Such paired Ga sites behaved as ion-exchange sites for capturing divalent cation, Co.
由Ga-O-Si-O-Ga序列表示的成对Ga位点首先在CHA型沸石骨架中通过在种子辅助水热条件下在富Ga无定形硅铝酸盐中预先形成的成对Ga物种的转录而有意形成。这种成对的Ga位点作为捕获二价阳离子Co的离子交换位点。
